卤素在金属表面的吸附

IF 8.2 1区化学 Q1 CHEMISTRY, PHYSICAL

Surface Science Reports Pub Date : 2018-06-01 DOI:10.1016/j.surfrep.2018.03.001

B.V. Andryushechkin , T.V. Pavlova , K.N. Eltsov

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引用次数: 28

摘要

本文综述了卤素与金属表面相互作用的实验和理论研究。重点放在最近用扫描隧道显微镜结合密度泛函理论计算进行的测量上。卤素相互作用后在金属表面形成的表面结构可分为三大类:化学吸附单层、表面卤化物和块状卤化物。单层结构的形成用表面相变来描述。表面卤化物相被认为是化学吸收卤素和本体卤化物之间的中间体。介绍了研究金属卤化反应动力学的现代理论方法。

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Adsorption of halogens on metal surfaces

This paper presents a review of the experimental and theoretical investigations of halogen interaction with metal surfaces. The emphasis was placed on the recent measurements performed with a scanning tunneling microscope in combination with density functional theory calculations. The surface structures formed on metal surface after halogen interaction are classified into three groups: chemisorbed monolayer, surface halide, bulk-like halide. Formation of monolayer structures is described in terms of surface phase transitions. Surface halide phases are considered to be intermediates between chemisorbed halogen and bulk halide. The modern theoretical approaches in studying the dynamics of metal halogenation reactions are also presented.

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来源期刊

Surface Science Reports 化学-物理：凝聚态物理

CiteScore

15.90

自引率

2.00%

发文量

审稿时长

178 days

期刊介绍： Surface Science Reports is a journal that specializes in invited review papers on experimental and theoretical studies in the physics, chemistry, and pioneering applications of surfaces, interfaces, and nanostructures. The topics covered in the journal aim to contribute to a better understanding of the fundamental phenomena that occur on surfaces and interfaces, as well as the application of this knowledge to the development of materials, processes, and devices. In this journal, the term "surfaces" encompasses all interfaces between solids, liquids, polymers, biomaterials, nanostructures, soft matter, gases, and vacuum. Additionally, the journal includes reviews of experimental techniques and methods used to characterize surfaces and surface processes, such as those based on the interactions of photons, electrons, and ions with surfaces.