外消旋腺苷5′-磷咪唑烷在Na(+)-蒙脱土上的非酶低聚反应。

H Urata, C Aono, N Ohmoto, Y Shimamoto, Y Kobayashi, M Akagi
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引用次数: 1

摘要

在这项研究中,我们研究了活化的外消旋单核苷酸在Na(+)-蒙脱土存在下的非酶低聚反应。激活的D-和l -单核苷酸通过寡聚反应形成长度达十聚体的低聚物。类似地,激活的外消旋单核苷酸的寡聚化导致形成低聚物直至八聚体。这些结果表明,蒙脱土催化外消旋单体的低聚是相当有效的,尽管它的效率略低于D-和l -单体。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Non-enzymatic oligomerization of racemic adenosine 5'-phosphorimidazolide on Na(+)-montmorillonite.

In this study, we have investigated non-enzymatic oligomerization of an activated racemic mononucleotide in the presence of Na(+)-montmorillonite. Oligomers up to the decamer in length were formed by oligomerization reactions of activated D- and L-mononucleotides. Similarly, oligomerization of an activated racemic mononucleotide results in the formation of oligomers up to the octamer. These results suggest that montmorillonite catalysis is quite efficient for the oligomerization of racemic monomers, though it is somewhat less efficient than that of D- and L-monomers.

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