氯硝基苯甲酸和对茴香胺组成的双组分分子晶体的柱状结构聚集产生手性。

Enantiomer Pub Date : 2002-11-01 DOI:10.1080/10242430215703
Teruki Sugiyama, Jiben Meng, Teruo Matsuura
{"title":"氯硝基苯甲酸和对茴香胺组成的双组分分子晶体的柱状结构聚集产生手性。","authors":"Teruki Sugiyama,&nbsp;Jiben Meng,&nbsp;Teruo Matsuura","doi":"10.1080/10242430215703","DOIUrl":null,"url":null,"abstract":"<p><p>Four two-component molecular crystals 1.2, 1.3, 1.4 and 1.5 composed of chloronitrobenzoic acids and p-anisidine as components have been prepared. Among these molecular crystals, 1.2 and 1.3 showed the generation of chirality (space group P2(1)) by aggregation of mutually parallel column structures with their 2(1) axes pointing in the same direction, and the others showed no chirality. This paper shows that the generation of chirality in a molecular crystal can be explained on the basis of the aggregation of column structures and that weaker intermolecular interactions affect the generation of chiral molecular crystal.</p>","PeriodicalId":11752,"journal":{"name":"Enantiomer","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Generation of chirality by the aggregation of column structures for two-component molecular crystals composed of chloronitrobenzoic acids and p-anisidine.\",\"authors\":\"Teruki Sugiyama,&nbsp;Jiben Meng,&nbsp;Teruo Matsuura\",\"doi\":\"10.1080/10242430215703\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Four two-component molecular crystals 1.2, 1.3, 1.4 and 1.5 composed of chloronitrobenzoic acids and p-anisidine as components have been prepared. Among these molecular crystals, 1.2 and 1.3 showed the generation of chirality (space group P2(1)) by aggregation of mutually parallel column structures with their 2(1) axes pointing in the same direction, and the others showed no chirality. This paper shows that the generation of chirality in a molecular crystal can be explained on the basis of the aggregation of column structures and that weaker intermolecular interactions affect the generation of chiral molecular crystal.</p>\",\"PeriodicalId\":11752,\"journal\":{\"name\":\"Enantiomer\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Enantiomer\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/10242430215703\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Enantiomer","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/10242430215703","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6

摘要

制备了以氯硝基苯甲酸和对茴香胺为组分的四种双组分分子晶体1.2、1.3、1.4和1.5。在这些分子晶体中,1.2和1.3通过2(1)轴指向相同方向的相互平行的柱状结构聚集产生手性(空间群P2(1)),而其他分子晶体则没有手性。本文表明,分子晶体中手性的产生可以用柱结构的聚集来解释,分子间较弱的相互作用影响手性分子晶体的产生。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Generation of chirality by the aggregation of column structures for two-component molecular crystals composed of chloronitrobenzoic acids and p-anisidine.

Four two-component molecular crystals 1.2, 1.3, 1.4 and 1.5 composed of chloronitrobenzoic acids and p-anisidine as components have been prepared. Among these molecular crystals, 1.2 and 1.3 showed the generation of chirality (space group P2(1)) by aggregation of mutually parallel column structures with their 2(1) axes pointing in the same direction, and the others showed no chirality. This paper shows that the generation of chirality in a molecular crystal can be explained on the basis of the aggregation of column structures and that weaker intermolecular interactions affect the generation of chiral molecular crystal.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信