奇偶违反的上升:太阳系内外的外手性

Enantiomer Pub Date : 2000-01-01
MacDermott
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引用次数: 0

摘要

我们回顾了Stephen Mason在同手性起源方面的最新进展,特别关注了对映体之间的违反奇偶能差(PVED)。我们总结了PVED的计算结果——包括我们自己和其他小组的计算结果——表明天然对映体在大多数情况下确实受到弱力的青睐。PVED不仅在解释生命起源中l -氨基酸的选择方面变得很重要,而且作为基础物理学的“分子足迹”,导致人们建议从PVED的未来光谱测量中获得温伯格角的值。外手性的新领域——地球以外的手性——现在正在兴起,有报道称陨石中存在过量的l -氨基酸,并有人建议在其他行星甚至其他太阳系中寻找同手性作为生命的标志。如果确实是PVED决定了生命的手性,我们就会期望在宇宙中到处都能找到l -氨基酸,而不是D。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The ascent of parity-violation: exochirality in the solar system and beyond

We review recent developments stemming from Stephen Mason's work on the origin of homochirality, focusing in particular on the parity-violating energy difference (PVED) between enantiomers. We summarize results of calculations of the PVED--both our own and those of other groups--which show that the natural enantiomers are indeed favoured by the weak force in most cases. The PVED has become important not only to explain the selection of the L-amino acids in the origin of life, but also as a "molecular footprint" of fundamental physics, leading to proposals to derive values of the Weinberg angle from future spectroscopic measurements of the PVED. The new field of exochirality--chirality outside the Earth--is now taking off, with reports of excesses of L-amino acids in meteorites, and proposals to look for homochirality as a signature of life on other planets and even in other solar systems. If it was indeed the PVED that determined life's handedness, we would expect to find L-amino acids rather than D everywhere in the universe.

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