机械化学反应对失活芳香族化合物的硝化作用

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2021-05-25 DOI:10.1016/j.tetlet.2021.153087

Jian-Wei Wu, Pu Zhang, Zhi-Xin Guo

引用次数: 3

摘要

以Fe(NO3)3·9H2O/P2O5为硝化剂，在高速球磨条件下，以优异的收率将多种失活芳烃硝化为相应的硝基衍生物。提出了一种具有面部、生态、安全、有效的硝化反应机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Nitration of deactivated aromatic compounds via mechanochemical reaction

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Nitration of deactivated aromatic compounds via mechanochemical reaction

A variety of deactivated arenes were nitrated to their corresponding nitro derivatives in excellent yields under high-speed ball milling condition using Fe(NO₃)₃·9H₂O/P₂O₅ as nitrating reagent. A radical involved mechanism was proposed for this facial, eco-friendly, safe, and effective nitration reaction.

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.