温度对弱配位溶剂半导体电沉积的影响

IF 4.5 3区 化学 Q1 Chemical Engineering
Alexander W. Black , Wenjian Zhang , Yasir J. Noori , Gillian Reid , Philip N. Bartlett
{"title":"温度对弱配位溶剂半导体电沉积的影响","authors":"Alexander W. Black ,&nbsp;Wenjian Zhang ,&nbsp;Yasir J. Noori ,&nbsp;Gillian Reid ,&nbsp;Philip N. Bartlett","doi":"10.1016/j.jelechem.2023.117638","DOIUrl":null,"url":null,"abstract":"<div><p>Temperature is an important variable in electrochemistry, increasing the operating temperature has the capacity to provide significant increases in mass transport and electron transfer rates. In the case of electrodeposition, it can also allow the deposition of crystalline material which would otherwise be amorphous when grown at lower temperatures. In this work we exploit a high boiling point, weakly coordinating solvent, o-dichlorobenzene, to electrodeposit the p-block semiconductors antimony and antimony telluride at temperatures up to 140 °C. The effect of the temperature on the morphology and crystallinity of the deposits is investigated using scanning electron microscopy, X-ray diffraction, Raman spectroscopy and optical microscopy. An attempt is also made to rationalise the role of temperature in electrodeposition and its influence on the aforementioned properties.</p></div>","PeriodicalId":50545,"journal":{"name":"Journal of Electroanalytical Chemistry","volume":"944 ","pages":"Article 117638"},"PeriodicalIF":4.5000,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Temperature effects on the electrodeposition of semiconductors from a weakly coordinating solvent\",\"authors\":\"Alexander W. Black ,&nbsp;Wenjian Zhang ,&nbsp;Yasir J. Noori ,&nbsp;Gillian Reid ,&nbsp;Philip N. Bartlett\",\"doi\":\"10.1016/j.jelechem.2023.117638\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Temperature is an important variable in electrochemistry, increasing the operating temperature has the capacity to provide significant increases in mass transport and electron transfer rates. In the case of electrodeposition, it can also allow the deposition of crystalline material which would otherwise be amorphous when grown at lower temperatures. In this work we exploit a high boiling point, weakly coordinating solvent, o-dichlorobenzene, to electrodeposit the p-block semiconductors antimony and antimony telluride at temperatures up to 140 °C. The effect of the temperature on the morphology and crystallinity of the deposits is investigated using scanning electron microscopy, X-ray diffraction, Raman spectroscopy and optical microscopy. An attempt is also made to rationalise the role of temperature in electrodeposition and its influence on the aforementioned properties.</p></div>\",\"PeriodicalId\":50545,\"journal\":{\"name\":\"Journal of Electroanalytical Chemistry\",\"volume\":\"944 \",\"pages\":\"Article 117638\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2023-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electroanalytical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1572665723004988\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Chemical Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electroanalytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1572665723004988","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Chemical Engineering","Score":null,"Total":0}
引用次数: 0

摘要

温度是电化学中的一个重要变量,提高操作温度可以显著提高质量传递率和电子传递率。在电沉积的情况下,它也可以允许结晶材料的沉积,否则在较低温度下生长时将是无定形的。在这项工作中,我们利用高沸点,弱配位溶剂,邻二氯苯,在高达140°C的温度下电沉积p-嵌段半导体锑和碲化锑。利用扫描电镜、x射线衍射、拉曼光谱和光学显微镜研究了温度对镀层形貌和结晶度的影响。本文还试图使温度在电沉积中的作用及其对上述性质的影响合理化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Temperature effects on the electrodeposition of semiconductors from a weakly coordinating solvent

Temperature is an important variable in electrochemistry, increasing the operating temperature has the capacity to provide significant increases in mass transport and electron transfer rates. In the case of electrodeposition, it can also allow the deposition of crystalline material which would otherwise be amorphous when grown at lower temperatures. In this work we exploit a high boiling point, weakly coordinating solvent, o-dichlorobenzene, to electrodeposit the p-block semiconductors antimony and antimony telluride at temperatures up to 140 °C. The effect of the temperature on the morphology and crystallinity of the deposits is investigated using scanning electron microscopy, X-ray diffraction, Raman spectroscopy and optical microscopy. An attempt is also made to rationalise the role of temperature in electrodeposition and its influence on the aforementioned properties.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Electroanalytical Chemistry
Journal of Electroanalytical Chemistry Chemical Engineering-General Chemical Engineering
CiteScore
7.50
自引率
6.70%
发文量
912
审稿时长
>12 weeks
期刊介绍: The Journal of Electroanalytical Chemistry is the foremost international journal devoted to the interdisciplinary subject of electrochemistry in all its aspects, theoretical as well as applied. Electrochemistry is a wide ranging area that is in a state of continuous evolution. Rather than compiling a long list of topics covered by the Journal, the editors would like to draw particular attention to the key issues of novelty, topicality and quality. Papers should present new and interesting electrochemical science in a way that is accessible to the reader. The presentation and discussion should be at a level that is consistent with the international status of the Journal. Reports describing the application of well-established techniques to problems that are essentially technical will not be accepted. Similarly, papers that report observations but fail to provide adequate interpretation will be rejected by the Editors. Papers dealing with technical electrochemistry should be submitted to other specialist journals unless the authors can show that their work provides substantially new insights into electrochemical processes.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信