1,3,5-三氟-2,4,6-三碘苯的单、二和三氮化反应

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-07-10 DOI:10.1007/s11172-024-4658-z

I. K. Yakushchenko, S. V. Chapyshev

引用次数: 0

摘要

研究了叠氮化钠对1,3,5-三氟-2,4,6-三碘苯的单、二、三氮化反应条件，通过不同的溶剂、温度和反应物的摩尔比，得到1-叠氮-3,5-二氟-2,4,6-三碘苯、1,3,5-三氮基-5-氟-2,4,6-三碘苯和1,3,5-三氮基-2,4,6-三碘苯，可作为光化学合成三碘化单、二、三腈的前驱体。

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Mono-, di-, and triazidation of 1,3,5-trifluoro-2,4,6-triiodobenzene

Conditions for mono-, di-, and triazidation of 1,3,5-trifluoro-2,4,6-triiodobenzene with sodium azide were developed varying solvents, temperature, and molar ratio of reactants to furnish 1-azido-3,5-difluoro-2,4,6-triiodobenzene, 1,3-diazido-5-fluoro-2,4,6-triiodobenzene, and 1,3,5-triazido-2,4,6-triiodobenzene, which can be used as precursors for photochemical synthesis of triiodinated mono-, di-, and trinitrenes.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.