基于二苯基膦酰乙酸和甲酸酰肼的新型含磷氨基脲和双脲类化合物

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-08-05 DOI:10.1134/S1070363225602923

A. O. Isaeva, R. N. Burangulova, I. A. Krutov, A. V. Shirshova, M. N. Sayfutdinova, A. I. Samigullina, E. L. Gavrilova

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引用次数: 0

摘要

提出了一种由二苯基膦酰乙酸和甲酸肼与各种异氰酸酯反应得到以前未知的酰基和甲酰氨基脲的方法。结果发现，根据温度、溶剂和试剂的比例不同，可以形成酰基和甲酰氨基脲的磷酸化产物，或以它们为基础的脲类化合物，或这两种化合物的混合物。双脲的生成过程是连续的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

New Phosphorus-Containing Semicarbazides and Bisureas Based on Diphenylphosphinylacetic and Formic Acids Hydrazides

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New Phosphorus-Containing Semicarbazides and Bisureas Based on Diphenylphosphinylacetic and Formic Acids Hydrazides

A method was proposed for obtaining previously unknown phosphorylated acyl- and formylsemicarbazides by the reaction of diphenylphosphinylacetic and formic acid hydrazides with various isocyanates. It was found that, depending on the temperature, solvent and reagent ratio, either phosphorylated acyl- and formylsemicarbazides, or bisureas based on them, or a mixture of these two compounds were formed. The process of bisurea formation is sequential.

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.