臭氧分解N-[2-（环己基-1-烯-1-基）-6-甲基苯基]-4-甲基苯磺酰胺时烯丙基羟基化产物的意外形成

IF 0.9 4区化学 Q4 CHEMISTRY, ORGANIC

Russian Journal of Organic Chemistry Pub Date : 2025-06-17 DOI:10.1134/S1070428025600299

R. R. Safargalin, R. R. Gataullin

引用次数: 0

摘要

臭氧分解N-[（2-环己基-1-烯-1-基）-6-甲基苯基]-4-甲基苯磺酰胺，然后用二甲基硫化物处理，得到预期的酮醛，4-甲基-N-[2-甲基-6-（6-氧己基）苯基]苯磺酰胺和意想不到的烯丙基羟基化产物N-[2-（6-羟基环己基-1-烯-1-基）-6-甲基苯基]-4-甲基苯磺酰胺的混合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Unexpected Formation of Allylic Hydroxylation Product in the Ozonolysis of N-[2-(Cyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide

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Unexpected Formation of Allylic Hydroxylation Product in the Ozonolysis of N-[2-(Cyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide

The ozonolysis of N-[(2-cyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide, followed by treatment with dimethyl sulfide gave a mixture of the expected keto aldehyde, 4-methyl-N-[2-methyl-6-(6-oxohexanoyl)phenyl]benzenesulfonamide and unexpected allylic hydroxylation product, N-[2-(6-hydroxycyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide.

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来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.