{"title":"铁钠对偶联反应","authors":"Jos Briggs-Pritchard, Michael L. Neidig","doi":"10.1038/s44160-025-00779-7","DOIUrl":null,"url":null,"abstract":"Organosodium reagents have long been considered too reactive for application in organic synthesis. Now, sodium-based nucleophiles can be used with iron catalysis to enable C(sp2) homo-coupling and C(sp2)–C(sp3) cross-coupling reactions.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"4 7","pages":"783-784"},"PeriodicalIF":20.0000,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Coupling reactions using iron–sodium pairs\",\"authors\":\"Jos Briggs-Pritchard, Michael L. Neidig\",\"doi\":\"10.1038/s44160-025-00779-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Organosodium reagents have long been considered too reactive for application in organic synthesis. Now, sodium-based nucleophiles can be used with iron catalysis to enable C(sp2) homo-coupling and C(sp2)–C(sp3) cross-coupling reactions.\",\"PeriodicalId\":74251,\"journal\":{\"name\":\"Nature synthesis\",\"volume\":\"4 7\",\"pages\":\"783-784\"},\"PeriodicalIF\":20.0000,\"publicationDate\":\"2025-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.nature.com/articles/s44160-025-00779-7\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"0\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://www.nature.com/articles/s44160-025-00779-7","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Organosodium reagents have long been considered too reactive for application in organic synthesis. Now, sodium-based nucleophiles can be used with iron catalysis to enable C(sp2) homo-coupling and C(sp2)–C(sp3) cross-coupling reactions.
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