以木质素为原料生产苯甲酸

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Zhaolin Dou, Ni Han, Liantong Guo, Bo Jiang, Zengxi Feng, Jiping Ma, Min Ji, Min Wang
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引用次数: 0

摘要

木质素是自然界中最丰富的可再生芳香资源。本文报道了一种新的生物精炼厂,通过两步法从木质素中生产苯甲酸。首先将还原催化分馏得到的木质素单体在多孔CoMoS (CoMoS- p)催化剂上加氢脱氧为烷基苯,CoMoS- p的多孔结构显著提高了加氢脱氧反应活性。然后以氧为氧化剂,在NHPI/Mn(OAc)2上氧化烷基苯生成苯甲酸。结果表明,从1克松木木质素中可以得到54毫克苯甲酸。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Production of benzoic acid from wood lignin
Lignin is the most abundant renewable aromatic recourses in nature. Herein we report a new biorefinery for the production of benzoic acid from lignin through a two-steps strategy. First the Reductive-catalytic-fractionation-obtained lignin monomers was hydro-deoxygenated to alkylbenzenes over a porous CoMoS (CoMoS-P) catalyst, the porous structure of CoMoS-P significantly improved the hydrodeoxygenation reactivity. Then alkylbenzenes was oxidized to benzoic acid over NHPI/Mn(OAc)2 with O2 as the oxidant. For a result, 54 mg of benzoic acid can be obtained from 1 g of pine wood lignin.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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