非那嗪基聚集诱导发射材料的模块化合成。

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-06-28 DOI:10.1021/acs.orglett.5c01638

Viktorija Miseljic, R. Nacif-Pimenta and Brian H. Northrop*,

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引用次数: 0

摘要

二（三苯基乙烯）功能化的邻苯二胺与邻醌容易缩合，得到了产率高的非那嗪类发光物质。荧光研究表明，在含水≥60%的四氢呋喃溶液中，四种新的吩那嗪衍生物均表现出聚集诱导发射（AIE）行为。通过动态光散射、共聚焦显微镜和扫描电子显微镜进一步研究了聚集体的大小和结构，每一种都显示随着水的百分比增加，大约球形颗粒的大小减小。

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Modular Synthesis of Phenazine-Based Aggregation-Induced Emission Materials

The facile condensation of bis(triphenylethylene)-functionalized ortho-phenylenediamine with ortho-quinones gives phenazine-based luminogens in high yield. Fluorescence studies demonstrate that each of the four new phenazine derivatives displays aggregation-induced emission (AIE) behavior in THF solutions containing ≥60% water. The sizes and structures of aggregates have been investigated further by dynamic light scattering, confocal microscopy, and scanning electron microscopy, each showing a decrease in the size of roughly spherical particles with increasing percentage of water.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.