有机光催化剂伊红Y在可见光下催化C - S键的形成

IF 2.7 3区 化学 Q2 CHEMISTRY, ORGANIC
Qinggang Mei, Qinghan Li
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引用次数: 0

摘要

由于C - S键广泛存在于许多重要的药物和天然生物化合物中,因此开发绿色高效的C - S键形成方法受到了合成化学家的极大关注。近年来,可见光促进的光化学有机转化引起了许多有机化学家的兴趣。与传统方法相比,可见光作为可再生能源的光氧化还原催化剂已被证明是一种温和而有力的工具,可以通过单电子转移(SET)过程促进有机分子的活化。因此,该策略已被广泛应用于C - C和C -杂原子键的形成。本文综述了近年来有机光催化剂伊红Y在可见光下促进碳硫键形成的研究成果,并对具有代表性的例子和反应机理进行了讨论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Visible-Light-Induced C─S Bond Formation Catalyzed by the Organic Photocatalyst Eosin Y

Visible-Light-Induced C─S Bond Formation Catalyzed by the Organic Photocatalyst Eosin Y

Visible-Light-Induced C─S Bond Formation Catalyzed by the Organic Photocatalyst Eosin Y

Visible-Light-Induced C─S Bond Formation Catalyzed by the Organic Photocatalyst Eosin Y

Visible-Light-Induced C─S Bond Formation Catalyzed by the Organic Photocatalyst Eosin Y

The development of green and efficient C─S bond formation methods has received significant attention from synthetic chemists because the C─S bonds widely occurs in many important drugs and natural biological compounds. In recent years, photochemical organic conversion promoted by visible light has attracted the interest of many organic chemists. Compared with the traditional methods, visible light as the photoredox catalysis of renewable energy has been proved to be a mild and powerful tool that can promote the activation of organic molecules through the single electron transfer process. Therefore, this strategy has been widely applied in the formation of C─C and C─heteroatom bonds. This article reviews the research results on the formation of carbon sulfur bond promoted by organic photocatalyst Eosin Y under visible light in recent years, and discusses representative examples and reaction mechanisms.

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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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