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Ti3C3@C2v(9)-C82：在富勒烯笼内的双蝶形三金属碳化物簇

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Chemical Communications Pub Date : 2025-05-20 DOI:10.1039/d5cc02276b
Zhiwen He , Zhengkai Cao , Yang-Rong Yao , Ning Chen
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引用次数: 0

摘要

史无前例的双蝶形Ti3C3簇在C82笼内稳定，形成了新型的三金属碳化物簇富勒烯Ti3C3@C2v(9)-C82。晶体学结果明确地揭示了一种罕见的Ti-C配位模式，这与T3C3@Ih(7)-C80内部的配位模式有很大不同，突出了富勒烯笼在确定受限金属团簇构型中的关键作用。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Ti3C3@C2v(9)-C82: a double-butterfly tri-metal carbide cluster inside a fullerene cage†

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Ti3C3@C2v(9)-C82: a double-butterfly tri-metal carbide cluster inside a fullerene cage†
An unprecedented double-butterfly Ti3C3 cluster was stabilized inside a C82 cage, forming a novel tri-metal carbide clusterfullerene, Ti3C3@C2v(9)-C82. The crystallographic results unambiguously reveal a rare Ti–C coordination mode, which differs significantly from that inside T3C3@Ih(7)-C80, highlighting the key role of fullerene cages in determining the configuration of confined metal clusters.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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