{"title":"含氯马酰亚胺部分的苯并-15冠-5基配体形成的三明治型钾阳离子配合物的晶体结构","authors":"Yuto Hirayama, Akitaka Ito and Rika Ochi","doi":"10.1039/D5CE00252D","DOIUrl":null,"url":null,"abstract":"<p >We developed a novel benzo-15-crown-5 (B15C5)-based organic ligand containing an <em>N</em>-phenylchloromaleimide moiety. Two geometrically different potassium cation (K<small><sup>+</sup></small>) complexes with a B15C5/K<small><sup>+</sup></small>/B15C5 sandwich structure were prepared and characterised <em>via</em> single-crystal X-ray diffraction.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 20","pages":" 3214-3218"},"PeriodicalIF":2.6000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal structures of sandwich-type potassium cation complexes formed from benzo-15-crown-5-based ligand containing a chloromaleimide moiety†\",\"authors\":\"Yuto Hirayama, Akitaka Ito and Rika Ochi\",\"doi\":\"10.1039/D5CE00252D\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >We developed a novel benzo-15-crown-5 (B15C5)-based organic ligand containing an <em>N</em>-phenylchloromaleimide moiety. Two geometrically different potassium cation (K<small><sup>+</sup></small>) complexes with a B15C5/K<small><sup>+</sup></small>/B15C5 sandwich structure were prepared and characterised <em>via</em> single-crystal X-ray diffraction.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 20\",\"pages\":\" 3214-3218\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d5ce00252d\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d5ce00252d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Crystal structures of sandwich-type potassium cation complexes formed from benzo-15-crown-5-based ligand containing a chloromaleimide moiety†
We developed a novel benzo-15-crown-5 (B15C5)-based organic ligand containing an N-phenylchloromaleimide moiety. Two geometrically different potassium cation (K+) complexes with a B15C5/K+/B15C5 sandwich structure were prepared and characterised via single-crystal X-ray diffraction.