5-乙酰基-2-氨基-4-（2-氟-苯基）-6-甲基-4- h -吡喃-3-碳腈二氯甲烷半磺酸盐。

IUCrData Pub Date : 2025-04-01 DOI:10.1107/S2414314625003372

Carren Nyapola , Sizwe J. Zamisa , Bernard Omondi , Eric M. Njogu

{"title":"5-乙酰基-2-氨基-4-（2-氟-苯基）-6-甲基-4- h -吡喃-3-碳腈二氯甲烷半磺酸盐。","authors":"Carren Nyapola , Sizwe J. Zamisa , Bernard Omondi , Eric M. Njogu","doi":"10.1107/S2414314625003372","DOIUrl":null,"url":null,"abstract":"<div><div>A two-dimensional supramolecular architecture mediated by N—H⋯N and N—H⋯O hydrogen bonds is formed in the crystal of the title compound.</div></div><div><div>The title compound, 2C<sub>15</sub>H<sub>13</sub>FN<sub>2</sub>O<sub>2</sub>·CH<sub>2</sub>Cl<sub>2</sub>, crystallizes with two main molecules in the asymmetric unit with a disordered dichloromethane solvent molecule. The dihedral angles between the fluoro phenyl ring and 4<em>H</em>-pyran ring are 74.36 (15) and 80.69 (15)° in the two molecules. In the crystal, N—H⋯N and N—H⋯O hydrogen bonds link the molecules into a two-dimensional supramolecular network propagating in the (100) plane.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (310KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"5-Acetyl-2-amino-4-(2-fluorophenyl)-6-methyl-4H-pyran-3-carbonitrile dichlomethane hemisolvate\",\"authors\":\"Carren Nyapola , Sizwe J. Zamisa , Bernard Omondi , Eric M. Njogu\",\"doi\":\"10.1107/S2414314625003372\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A two-dimensional supramolecular architecture mediated by N—H⋯N and N—H⋯O hydrogen bonds is formed in the crystal of the title compound.</div></div><div><div>The title compound, 2C<sub>15</sub>H<sub>13</sub>FN<sub>2</sub>O<sub>2</sub>·CH<sub>2</sub>Cl<sub>2</sub>, crystallizes with two main molecules in the asymmetric unit with a disordered dichloromethane solvent molecule. The dihedral angles between the fluoro phenyl ring and 4<em>H</em>-pyran ring are 74.36 (15) and 80.69 (15)° in the two molecules. In the crystal, N—H⋯N and N—H⋯O hydrogen bonds link the molecules into a two-dimensional supramolecular network propagating in the (100) plane.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (310KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"10 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314625000240\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314625000240","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

标题化合物2C15H13FN2O2·CH2Cl2在不对称单元中与两个主分子与无序二氯甲烷溶剂分子结晶。在两个分子中，氟苯基环和4h -吡喃环的二面角分别为74.36（15）°和80.69（15）°。在晶体中，N- h⋯N和N- h⋯O氢键将分子连接成在（100）平面上传播的二维超分子网络。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

5-Acetyl-2-amino-4-(2-fluorophenyl)-6-methyl-4H-pyran-3-carbonitrile dichlomethane hemisolvate

A two-dimensional supramolecular architecture mediated by N—H⋯N and N—H⋯O hydrogen bonds is formed in the crystal of the title compound.

The title compound, 2C₁₅H₁₃FN₂O₂·CH₂Cl₂, crystallizes with two main molecules in the asymmetric unit with a disordered dichloromethane solvent molecule. The dihedral angles between the fluoro phenyl ring and 4H-pyran ring are 74.36 (15) and 80.69 (15)° in the two molecules. In the crystal, N—H⋯N and N—H⋯O hydrogen bonds link the molecules into a two-dimensional supramolecular network propagating in the (100) plane.

Download: Download high-res image (310KB)
Download: Download full-size image

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

IUCrData

CiteScore

0.30

自引率

0.00%

发文量