Dan Li*, Xiazhen Zhang, Xue Meng, Longxia Hao, Yixin Li and Guoqing Sui,
{"title":"碳酸二甲酯+肉豆肉酸甲酯+ 1-己醇三元混合物及其二元混合物密度和粘度的实验研究","authors":"Dan Li*, Xiazhen Zhang, Xue Meng, Longxia Hao, Yixin Li and Guoqing Sui, ","doi":"10.1021/acs.jced.4c0074510.1021/acs.jced.4c00745","DOIUrl":null,"url":null,"abstract":"<p >The density and dynamic viscosity of the ternary system (dimethyl carbonate + methyl myristate + 1-hexanol) and the related binary mixtures (dimethyl carbonate + methyl myristate), (dimethyl carbonate + 1-hexanol), and (methyl myristate + 1-hexanol) were experimentally determined in the temperature range <i>T</i> = 293.15–323.15 K, which were applied to obtain the excess molar volume (<i>V</i><sub>m</sub><sup>E</sup>) and deviation in viscosity (Δη) of ternary and its related binary systems. Redlich–Kister, Cibulka, and Singh equations were used to estimate <i>V</i><sub>m</sub><sup>E</sup> and Δη of ternary mixtures. The <i>V</i><sub>m</sub><sup>E</sup> consistently exhibited positive values for all studied systems, while the Δη values were negative, which provided data support for the thermodynamic study and application of the biodiesel mixed fuel system.</p>","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"70 5","pages":"1946–1955 1946–1955"},"PeriodicalIF":2.0000,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental Investigations of Densities and Viscosities for the Ternary Mixture of (Dimethyl Carbonate + Methyl Myristate + 1-Hexanol) and Corresponding Binary Mixtures\",\"authors\":\"Dan Li*, Xiazhen Zhang, Xue Meng, Longxia Hao, Yixin Li and Guoqing Sui, \",\"doi\":\"10.1021/acs.jced.4c0074510.1021/acs.jced.4c00745\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The density and dynamic viscosity of the ternary system (dimethyl carbonate + methyl myristate + 1-hexanol) and the related binary mixtures (dimethyl carbonate + methyl myristate), (dimethyl carbonate + 1-hexanol), and (methyl myristate + 1-hexanol) were experimentally determined in the temperature range <i>T</i> = 293.15–323.15 K, which were applied to obtain the excess molar volume (<i>V</i><sub>m</sub><sup>E</sup>) and deviation in viscosity (Δη) of ternary and its related binary systems. Redlich–Kister, Cibulka, and Singh equations were used to estimate <i>V</i><sub>m</sub><sup>E</sup> and Δη of ternary mixtures. The <i>V</i><sub>m</sub><sup>E</sup> consistently exhibited positive values for all studied systems, while the Δη values were negative, which provided data support for the thermodynamic study and application of the biodiesel mixed fuel system.</p>\",\"PeriodicalId\":42,\"journal\":{\"name\":\"Journal of Chemical & Engineering Data\",\"volume\":\"70 5\",\"pages\":\"1946–1955 1946–1955\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2025-04-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical & Engineering Data\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.jced.4c00745\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical & Engineering Data","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.jced.4c00745","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Experimental Investigations of Densities and Viscosities for the Ternary Mixture of (Dimethyl Carbonate + Methyl Myristate + 1-Hexanol) and Corresponding Binary Mixtures
The density and dynamic viscosity of the ternary system (dimethyl carbonate + methyl myristate + 1-hexanol) and the related binary mixtures (dimethyl carbonate + methyl myristate), (dimethyl carbonate + 1-hexanol), and (methyl myristate + 1-hexanol) were experimentally determined in the temperature range T = 293.15–323.15 K, which were applied to obtain the excess molar volume (VmE) and deviation in viscosity (Δη) of ternary and its related binary systems. Redlich–Kister, Cibulka, and Singh equations were used to estimate VmE and Δη of ternary mixtures. The VmE consistently exhibited positive values for all studied systems, while the Δη values were negative, which provided data support for the thermodynamic study and application of the biodiesel mixed fuel system.
期刊介绍：
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.
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