外封面:由N杂三角烯组成的螺旋手性混价体系:阳离子物种的π膨胀稳定化(新)。化学16/2025)

Jan Borstelmann, Simon Zank, Marcel Krug, Georg Berger, Nina Fröhlich, Gabriel Glotz, Frederik Gnannt, Lars Schneider, Frank Rominger, Felix Deschler, Timothy Clark, Georg Gescheidt, Dirk M. Guldi, Milan Kivala
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引用次数: 0

摘要

封面艺术作品可视化二聚体n -异三角烯在螺旋楼梯前反映其螺旋手性。蓝色球体代表氧化还原活性氮,连接的充满活力的途径象征电荷转移,导致p共轭螺旋烯主链实现混合价态。发光的橙色螺旋说明了该化合物发射圆偏振光的能力,这一特性与未来低环境影响的热带应用有关。阅读Dirk M. Guldi, Milan Kivala等人的研究文章(e202423516)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Outside Front Cover: Helically Chiral Mixed-Valence Systems Comprising N Heterotriangulenes: Stabilization of the Cationic Species by π Expansion (Angew. Chem. 16/2025)

Outside Front Cover: Helically Chiral Mixed-Valence Systems Comprising N Heterotriangulenes: Stabilization of the Cationic Species by π Expansion (Angew. Chem. 16/2025)

The cover artwork visualizes the dimeric N-heterotriangulene in front of a spiral staircase reflecting its helical chirality. The blue spheres represent the redox-active nitrogens, the connecting vibrant pathway symbolizes the charge transfer leading to a mixed-valence state enabled by the p-conjugated helicene backbone. The glowing orange helix illustrates the compound's ability to emit circularly polarized light, a property relevant to future chiroptical applications with low environmental impact. Read more in the Research Article (e202423516) by Dirk M. Guldi, Milan Kivala et al.

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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