内页图片

IF 5.5 1区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chinese Journal of Chemistry Pub Date : 2025-04-15 DOI:10.1002/cjoc.70062

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引用次数: 0

摘要

建立了连续流电化学将α-氨基酸直接脱羧磷酸化为α-氨基膦酸盐的电化学方法。该方法消除了对强氧化剂和多步骤过程的需要，提供了一种直接且可扩展的方法。其成功的关键是在酸性条件下在阳极表面建立微环境，促进选择性脱羧和C-P键的形成。Xu等人在第1167-1172页的文章中讨论了更多细节。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Inside Cover Picture

An electrochemical method is developed for the direct decarboxylative phosphorylation of α-amino acids to α-amino phosphonates using continuous-flow electrochemistry. The method eliminates the need for strong oxidants and multi-step processes, offering a straightforward and scalable approach. Key to its success is the establishment of a microenvironment on the anode surface in acidic conditions, facilitating selective decarboxylation and C—P bond formation. More details are discussed in the article by Xu et al. on pages 1167—1172.

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来源期刊

Chinese Journal of Chemistry 化学-化学综合

CiteScore

8.80

自引率

14.80%

发文量

422

审稿时长

1.7 months

期刊介绍： The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.