高能硼基纳米花状复合材料的快速构建和能量释放效率

IF 3.5 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
Qian Huang, Zhiwen Lin, Kaige Guo, Chengchen Zhang, Yikai Wang, Chenguang Zhu, Debin Ni, Yuxin Jia, Mingxing Zhang
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引用次数: 0

摘要

为了解决硼(B)的点火和燃烧问题,以硼化镁为原料,通过蚀刻和结晶合成了B@Mg@AP高能硼基纳米花复合材料。B@Mg@AP高能复合材料表面包裹有纳米花状高氯酸铵(AP),核心处硼(B)和镁(Mg)交替排列。镁(Mg)和过氯酸铵(AP)的掺入提高了硼(B)的反应活性和燃烧效率。点火燃烧试验表明,与B/AP体系相比,相同配比下B@Mg@AP试样的放热量提高了452.1%,最高火焰温度提高了约37.4%。与硼(B)相比,B@Mg@AP复合材料的最大热值提高了99.3%,燃烧效率提高了31.12%。B@Mg@AP复合材料的成功合成有望促进硼基火箭冲压发动机的应用和发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Rapid construction and energy release efficiency of high energy boron based nanoflower-like composites

Rapid construction and energy release efficiency of high energy boron based nanoflower-like composites
To address the ignition and combustion issues associated with boron (B), B@Mg@AP high-energy boron-based nanoflower composites were synthesized through etching and crystallization, utilizing magnesium boride as the raw material. The B@Mg@AP high-energy composite is coated with a nano-flower-like ammonium perchlorate (AP), with boron (B) and magnesium (Mg) arranged alternately in the core. The inclusion of magnesium (Mg) and ammonium perchlorate (AP) enhances the reactivity and combustion efficiency of boron (B). The ignition combustion tests indicate that, compared to the B/AP system, the heat release of the B@Mg@AP sample at the same ratio has increased by 452.1%, with the maximum flame temperature rising by approximately 37.4%. In comparison to boron (B), the maximum calorific value of the B@Mg@AP composite has risen by 99.3%, while the combustion efficiency has improved by 31.12%. The successful synthesis of B@Mg@AP composites is expected to facilitate the application and advancement of boron-based rocket ramjet engines.
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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