（5,6-二甲基-1,10-菲罗啉）（2-{[2-（二苯基-磷基）苄基-氨基]氨基}-乙二胺）-铂（II）硝酸甲醇溶剂

IF 0.6 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2025-04-01 DOI:10.1107/S2056989025001847

Ashley Jurisinec , Yingjie Zhang , Janice R. Aldrich-Wright

{"title":"（5,6-二甲基-1,10-菲罗啉）（2-{[2-（二苯基-磷基）苄基-氨基]氨基}-乙二胺）-铂（II）硝酸甲醇溶剂","authors":"Ashley Jurisinec , Yingjie Zhang , Janice R. Aldrich-Wright","doi":"10.1107/S2056989025001847","DOIUrl":null,"url":null,"abstract":"<div><div>The title platinum(II) complex exhibits a distorted square-planar geometry. Intra- and intermolecular π-stacking interactions are observed between the phenanthroline and phosphine rings while hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.</div></div><div><div>The title compound, [Pt(C<sub>14</sub>H<sub>12</sub>N<sub>2</sub>)(C<sub>21</sub>H<sub>21</sub>N<sub>2</sub>P)](NO<sub>3</sub>)<sub>2</sub>·2CH<sub>3</sub>OH, is a platinum(II) complex, which crystallizes in a monoclinic (<em>P</em>2<sub>1</sub>/<em>c</em>) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine ligand. The structure reveals both intra- and intermolecular π-stacking interactions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.</div></div>","PeriodicalId":7367,"journal":{"name":"Acta Crystallographica Section E: Crystallographic Communications","volume":"81 4","pages":"Pages 275-278"},"PeriodicalIF":0.6000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"(5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine)platinum(II) dinitrate methanol disolvate\",\"authors\":\"Ashley Jurisinec , Yingjie Zhang , Janice R. Aldrich-Wright\",\"doi\":\"10.1107/S2056989025001847\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The title platinum(II) complex exhibits a distorted square-planar geometry. Intra- and intermolecular π-stacking interactions are observed between the phenanthroline and phosphine rings while hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.</div></div><div><div>The title compound, [Pt(C<sub>14</sub>H<sub>12</sub>N<sub>2</sub>)(C<sub>21</sub>H<sub>21</sub>N<sub>2</sub>P)](NO<sub>3</sub>)<sub>2</sub>·2CH<sub>3</sub>OH, is a platinum(II) complex, which crystallizes in a monoclinic (<em>P</em>2<sub>1</sub>/<em>c</em>) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine ligand. The structure reveals both intra- and intermolecular π-stacking interactions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.</div></div>\",\"PeriodicalId\":7367,\"journal\":{\"name\":\"Acta Crystallographica Section E: Crystallographic Communications\",\"volume\":\"81 4\",\"pages\":\"Pages 275-278\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2025-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Crystallographica Section E: Crystallographic Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2056989025000568\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section E: Crystallographic Communications","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2056989025000568","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}

引用次数: 0

摘要

标题铂（II）配合物呈现出扭曲的方形平面几何形状。邻菲罗啉环和膦环之间存在分子内和分子间的π堆积相互作用，配合离子、硝酸盐反离子和溶剂分子之间存在氢键。标题化合物[Pt(C14H12N2)(C21H21N2P)](NO3)2·2CH3OH是一种铂（II）配合物，在单斜（P21/c）空间群中结晶。该配合物呈扭曲的方平面结构，包括一个单齿5,6-二甲基-1,10-菲罗啉配体和一个三齿2-{[2-（二苯基-磷基）苄基]氨基}-乙二胺配体。该结构揭示了菲罗啉环和磷化氢环在分子内和分子间的π堆积相互作用。在络合离子、硝酸反离子和溶剂分子之间观察到氢键。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

(5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine)platinum(II) dinitrate methanol disolvate

The title platinum(II) complex exhibits a distorted square-planar geometry. Intra- and intermolecular π-stacking interactions are observed between the phenanthroline and phosphine rings while hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.

The title compound, [Pt(C₁₄H₁₂N₂)(C₂₁H₂₁N₂P)](NO₃)₂·2CH₃OH, is a platinum(II) complex, which crystallizes in a monoclinic (P2₁/c) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine ligand. The structure reveals both intra- and intermolecular π-stacking interactions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.