{"title":"四唑类粘合剂对高能材料的热裂解特性研究","authors":"M. V. Komarova, A. G. Vakutin","doi":"10.1134/S0012501625600123","DOIUrl":null,"url":null,"abstract":"<p>The paper presents the results of experimental studies of the thermal characteristics of high-energy compounds based on low-sensitivity oxidants, 5-nitro-1,2-dihydro-3<i>H</i>-1,2,4-triazin-3-one, 1,3,5-triamino-2,4,6-trinitrobenzene, and 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0<sup>5,9</sup>.0<sup>3,11</sup>]dodecane, and tetrazole binders based on allylated poly-<i>N</i>-methyl-5-vinyltetrazole (PMVT-A). Differential scanning calorimetry and thermogravimetric analysis were used to study the thermal properties of the compositions, the features of thermolysis, and the chemical compatibility of the components. It was shown that binders based on PMVT-A plasticized with propylene glycol dinitrate or nitroamine/nitroester mixtures are fully compatible with the crystalline oxidant, 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetrcyclone[5.5.0.0<sup>5,9</sup>.0<sup>3,11</sup>]dodecane, and completely incompatible with 5-nitro-1,2-dihydro-3H-1,2,4-triazine-3<i>-</i>one<i>.</i></p>","PeriodicalId":532,"journal":{"name":"Doklady Physical Chemistry","volume":"516 1-2","pages":"45 - 49"},"PeriodicalIF":1.1000,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Features of Thermolysis of High-Energy Materials with Tetrazole Binders\",\"authors\":\"M. V. Komarova, A. G. Vakutin\",\"doi\":\"10.1134/S0012501625600123\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The paper presents the results of experimental studies of the thermal characteristics of high-energy compounds based on low-sensitivity oxidants, 5-nitro-1,2-dihydro-3<i>H</i>-1,2,4-triazin-3-one, 1,3,5-triamino-2,4,6-trinitrobenzene, and 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0<sup>5,9</sup>.0<sup>3,11</sup>]dodecane, and tetrazole binders based on allylated poly-<i>N</i>-methyl-5-vinyltetrazole (PMVT-A). Differential scanning calorimetry and thermogravimetric analysis were used to study the thermal properties of the compositions, the features of thermolysis, and the chemical compatibility of the components. It was shown that binders based on PMVT-A plasticized with propylene glycol dinitrate or nitroamine/nitroester mixtures are fully compatible with the crystalline oxidant, 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetrcyclone[5.5.0.0<sup>5,9</sup>.0<sup>3,11</sup>]dodecane, and completely incompatible with 5-nitro-1,2-dihydro-3H-1,2,4-triazine-3<i>-</i>one<i>.</i></p>\",\"PeriodicalId\":532,\"journal\":{\"name\":\"Doklady Physical Chemistry\",\"volume\":\"516 1-2\",\"pages\":\"45 - 49\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2025-03-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Doklady Physical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0012501625600123\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady Physical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0012501625600123","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Features of Thermolysis of High-Energy Materials with Tetrazole Binders
The paper presents the results of experimental studies of the thermal characteristics of high-energy compounds based on low-sensitivity oxidants, 5-nitro-1,2-dihydro-3H-1,2,4-triazin-3-one, 1,3,5-triamino-2,4,6-trinitrobenzene, and 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.05,9.03,11]dodecane, and tetrazole binders based on allylated poly-N-methyl-5-vinyltetrazole (PMVT-A). Differential scanning calorimetry and thermogravimetric analysis were used to study the thermal properties of the compositions, the features of thermolysis, and the chemical compatibility of the components. It was shown that binders based on PMVT-A plasticized with propylene glycol dinitrate or nitroamine/nitroester mixtures are fully compatible with the crystalline oxidant, 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetrcyclone[5.5.0.05,9.03,11]dodecane, and completely incompatible with 5-nitro-1,2-dihydro-3H-1,2,4-triazine-3-one.
期刊介绍：
Doklady Physical Chemistry is a monthly journal containing English translations of current Russian research in physical chemistry from the Physical Chemistry sections of the Doklady Akademii Nauk (Proceedings of the Russian Academy of Sciences). The journal publishes the most significant new research in physical chemistry being done in Russia, thus ensuring its scientific priority. Doklady Physical Chemistry presents short preliminary accounts of the application of the state-of-the-art physical chemistry ideas and methods to the study of organic and inorganic compounds and macromolecules; polymeric, inorganic and composite materials as well as corresponding processes. The journal is intended for scientists in all fields of chemistry and in interdisciplinary sciences.
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