四-4-羧基酞菁羟铝在298.15 K KOH水溶液中溶解的热化学性质

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2025-03-17 DOI:10.1134/S0036024424702479

P. D. Krutov, V. E. Maizlish, O. N. Krutova, T. R. Usacheva, M. I. Bazanov, M. V. Chislov, E. E. Kiptikova

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引用次数: 0

摘要

对四-4-羧基酞菁羟铝进行了研究。在298.15 K的温度下，用直接量热法测定了结晶酞菁在不同KOH浓度水溶液中溶解的热效应。利用HEAT程序计算了逐步解离AlOHРс（4- cooh）4的热效应。所研究化合物的燃烧焓用IKA C6000等温量热计（炸弹量热计）测定，并用于计算AlOHРс（4- cooh）4及其在水溶液中解离产物的标准生成焓。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Thermochemistry of the Dissolution of Tetra-4-carboxyphthalocyanine Hydroxyaluminum in Aqueous Solutions of KOH at 298.15 K

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Thermochemistry of the Dissolution of Tetra-4-carboxyphthalocyanine Hydroxyaluminum in Aqueous Solutions of KOH at 298.15 K

A study is performed of tetra-4-carboxyphthalocyanine hydroxyaluminum. The thermal effects of the dissolution of crystalline phthalocyanine in aqueous solutions with different concentrations of KOH are determined via direct calorimetry at a temperature of 298.15 K. The thermal effects of stepwise dissociation AlOHРс(4-COOH)₄ are calculated using the HEAT computer program. The enthalpies of combustion of the studied compound are determined with an IKA C6000 isoperibol calorimeter (bomb calorimetry) and used to calculate the standard enthalpies of formation of AlOHРс(4-COOH)₄ along with products of its dissociation in aqueous solutions.

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.