封面专题:揭示镍(II)五齿配体配合物在芳香氧化中的催化活性(ChemCatChem 6/2025)

IF 3.9 3区 化学 Q2 CHEMISTRY, PHYSICAL
ChemCatChem Pub Date : 2025-03-17 DOI:10.1002/cctc.202580602
Anjana Rajeev, Sethuraman Muthuramalingam, Visvesvarar Pitchai Murugan, Miquel Costas, Prabha Vadivelu, Muniyandi Sankaralingam
{"title":"封面专题:揭示镍(II)五齿配体配合物在芳香氧化中的催化活性(ChemCatChem 6/2025)","authors":"Anjana Rajeev,&nbsp;Sethuraman Muthuramalingam,&nbsp;Visvesvarar Pitchai Murugan,&nbsp;Miquel Costas,&nbsp;Prabha Vadivelu,&nbsp;Muniyandi Sankaralingam","doi":"10.1002/cctc.202580602","DOIUrl":null,"url":null,"abstract":"<p><b>The Cover Feature</b> depicts the hydroxylation of benzene to phenol in the presence of a nickel pentadentate catalyst and hydrogen peroxide. The highly inert nature of the C─H bonds of benzene is represented by a spherical cage secured with a locked chain. However, the powerful nickel catalyst and oxidant act as a key, facilitating the selective oxidation of one of the C─H bonds to produce phenol. More information can be found in the Research Article by M. Sankaralingam and co-workers (DOI: 10.1002/cctc.202401645).\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 6","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202580602","citationCount":"0","resultStr":"{\"title\":\"Cover Feature: Unveiling the Catalytic Activity of Nickel(II) Complexes of Pentadentate Ligands in Aromatic Oxidations (ChemCatChem 6/2025)\",\"authors\":\"Anjana Rajeev,&nbsp;Sethuraman Muthuramalingam,&nbsp;Visvesvarar Pitchai Murugan,&nbsp;Miquel Costas,&nbsp;Prabha Vadivelu,&nbsp;Muniyandi Sankaralingam\",\"doi\":\"10.1002/cctc.202580602\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>The Cover Feature</b> depicts the hydroxylation of benzene to phenol in the presence of a nickel pentadentate catalyst and hydrogen peroxide. The highly inert nature of the C─H bonds of benzene is represented by a spherical cage secured with a locked chain. However, the powerful nickel catalyst and oxidant act as a key, facilitating the selective oxidation of one of the C─H bonds to produce phenol. More information can be found in the Research Article by M. Sankaralingam and co-workers (DOI: 10.1002/cctc.202401645).\\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":141,\"journal\":{\"name\":\"ChemCatChem\",\"volume\":\"17 6\",\"pages\":\"\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-03-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202580602\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemCatChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cctc.202580602\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemCatChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cctc.202580602","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

封面特征描述了在五齿酸镍催化剂和过氧化氢存在下苯羟基化成苯酚的过程。苯的C─H键的高度惰性表现为一个用锁链固定的球形笼。然而,强大的镍催化剂和氧化剂起到了关键作用,促进了其中一个C─H键的选择性氧化产生苯酚。更多信息可以在M. Sankaralingam及其同事的研究文章中找到(DOI: 10.1002/cctc.202401645)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Cover Feature: Unveiling the Catalytic Activity of Nickel(II) Complexes of Pentadentate Ligands in Aromatic Oxidations (ChemCatChem 6/2025)

Cover Feature: Unveiling the Catalytic Activity of Nickel(II) Complexes of Pentadentate Ligands in Aromatic Oxidations (ChemCatChem 6/2025)

The Cover Feature depicts the hydroxylation of benzene to phenol in the presence of a nickel pentadentate catalyst and hydrogen peroxide. The highly inert nature of the C─H bonds of benzene is represented by a spherical cage secured with a locked chain. However, the powerful nickel catalyst and oxidant act as a key, facilitating the selective oxidation of one of the C─H bonds to produce phenol. More information can be found in the Research Article by M. Sankaralingam and co-workers (DOI: 10.1002/cctc.202401645).

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ChemCatChem
ChemCatChem 化学-物理化学
CiteScore
8.10
自引率
4.40%
发文量
511
审稿时长
1.3 months
期刊介绍: With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信