包埋苯的己葡萄素（2.1.2.1.2.1）金属离子控制构型及1O2生成能力

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-03-11 DOI:10.1039/D5DT00036J

Jinrong Wu, Xiaojuan Lv, Zhaoli Xue, Yue Wang, Fengxian Qiu and Songlin Xue

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引用次数: 0

摘要

发现了包埋苯的8字形六葡萄素（2.1.2.1.2.1）的10族金属配合物。得到了单ni (II) 1Ni和双pd (II) 2Pd配合物。2Pd的晶体结构显示两个Pd（II）离子与6个N原子配位，两个Pd（II）离子由一个Cl原子桥接，并伴有一个旋转的吡啶单元。黄色激光束照射下1Ni和2Pd的结构和1O2生成研究表明，插入的金属离子可以调控己葡萄素（2.1.2.1.2.1）的分子结构和理化性质。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Metal ions control configuration and 1O2 generation capacity of hexaphyrin(2.1.2.1.2.1) with embedded benzene†

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Metal ions control configuration and 1O2 generation capacity of hexaphyrin(2.1.2.1.2.1) with embedded benzene†

Group 10 metal complexes of figure-of-eight–shaped hexaphyrin(2.1.2.1.2.1) with embedded benzene were revealed. Mono-Ni(II) 1Ni and bis-Pd(II) 2Pd complexes were obtained. Inspection of the crystal structure of 2Pd showed two Pd(II) ions coordinated with six N atoms and two Pd(II) ions bridged by a Cl atom accompanied by rotation of one pyrrolic unit. The structures and ¹O₂ generation studies of 1Ni and 2Pd under yellow laser beam irradiation indicated that the molecular structural and physicochemical properties of hexaphyrin(2.1.2.1.2.1) can be regulated and controlled by inserted metal ions.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.