正电子湮没法研究α-氧化铝填充HDPE纳米复合材料的表面微观结构

IF 2.6 4区 化学 Q3 POLYMER SCIENCE
Mahdi Ghasemifard, Misagh Ghamari, Murat Yavuz Yener, Cumali Tav, Ugur Yahsi
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引用次数: 0

摘要

采用热压法制备了不同重量分数(0.5 wt%、1 wt%、1.5 wt%、2 wt%、2.5 wt%和3 wt%)的高密度聚乙烯(HDPE)纳米复合材料。x射线衍射(XRD)结果表明,增加氧化铝的重量百分比对初始半结晶度没有显著影响。原子力显微镜(AFM)图像显示,在较高的氧化铝含量下,实现高表面均匀性是可能的。利用正电子湮灭寿命谱(PALS)和低能正电子束技术(LEPB)研究了自由体积的大小、浓度和形状。正电子湮没光谱结果表明,增加氧化铝的重量百分比会降低自由体积结构的尺寸、形状和均匀性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Examination of the surface microstructure of α-alumina filled HDPE nanocomposites using positron annihilation methods

High-density polyethylene (HDPE) nanocomposites with alpha alumina nanoparticles at various weight fractions (0.5 wt%, 1 wt%, 1.5 wt%, 2 wt%, 2.5 wt%, and 3 wt%) were successfully synthesized using the hot press method. X-ray diffraction (XRD) results revealed that increasing the weight percentage of alumina had no significant effect on the initial semi-crystallinity. Atomic force microscopy (AFM) images revealed that achieving high surface homogeneity is possible at higher alumina contents. Positron annihilation lifetime spectroscopy (PALS) and low energy positron beam technique (LEPB) were used to investigate the size, concentration and shape of the free volume. The results from positron annihilation spectroscopes indicated that increasing the weight percentage of alumina reduces the size, shape, and homogeneity of free volume structure.

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来源期刊
Journal of Polymer Research
Journal of Polymer Research 化学-高分子科学
CiteScore
4.70
自引率
7.10%
发文量
472
审稿时长
3.6 months
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including: polymer synthesis; polymer reactions; polymerization kinetics; polymer physics; morphology; structure-property relationships; polymer analysis and characterization; physical and mechanical properties; electrical and optical properties; polymer processing and rheology; application of polymers; supramolecular science of polymers; polymer composites.
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