与循环伏安法耦合的空间电荷分布测量

IF 1.9 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC
Mathilde Arnaud , Yann Walter , Amina Cheutin , Zehui Zhou , Rémi Federicci , Stéphane Holé , Brigitte Leridon
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引用次数: 0

摘要

了解储能装置中的电极-电解质界面仍然是改进这些系统的一个重要挑战。本文介绍了一种将循环伏安法与压力波传播法相结合的操作技术。该技术已应用于含有银或金电极的RbOH陶瓷,揭示了其氧化过程中不同的空间电荷分布。此外,还采用该实验方法对NaCl溶液中铝的腐蚀进行了监测。该方法提供了对充放电循环过程中静电电荷动力学的见解,并能够从固体-液体和固体-固体界面收集关键信息。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Operando space charge distribution measurements coupled with cyclic voltammetry
Understanding the electrode–electrolyte interface in energy storage devices remains an important challenge for the improvement of these systems. This paper introduces an operando technique that couples cyclic voltammetry with a system implementing the Pressure-Wave-Propagation method. This technique has been applied to RbOH ceramics containing either silver or gold electrodes, revealing different space charge distributions during their oxidation processes. In addition, this experimental method was employed to monitor aluminum corrosion in the presence of a NaCl solution. This method provides insights on the dynamics of electrostatic charges during charging–discharging cycles and enables to gather critical information from solid–liquid and solid–solid interfaces.
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来源期刊
Journal of Electrostatics
Journal of Electrostatics 工程技术-工程:电子与电气
CiteScore
4.00
自引率
11.10%
发文量
81
审稿时长
49 days
期刊介绍: The Journal of Electrostatics is the leading forum for publishing research findings that advance knowledge in the field of electrostatics. We invite submissions in the following areas: Electrostatic charge separation processes. Electrostatic manipulation of particles, droplets, and biological cells. Electrostatically driven or controlled fluid flow. Electrostatics in the gas phase.
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