Wen-Wen Zhang, Quannan Wang, Chao Zheng, Shu-Li You
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Rhodium-Catalyzed Atroposelective C–H Alkylation of 1-Aryl Isoquinoline Derivatives with Cyclopropanols
Highly efficient synthesis of axially chiral biaryls bearing a β-aryl ketone framework is achieved by an atroposelective C–H alkylation reaction of 1-aryl isoquinoline derivatives with cyclopropanols. Judiciously choosing SPINOL-derived trisubstituted SCpRh as the catalyst is crucial for the desired asymmetric alkylation reaction over the competitive formation of alkenylation byproducts, delivering the target axially chiral biaryls in 40–99% yields and 48–97% ee. Further mechanistic studies suggested that Rh-catalyzed C–H bond cleavage serves as the turnover-limiting step, while the Cu-mediated transformation of cyclopropyl alcohols into their corresponding enones is established as the key source of the active alkylation reagents.
期刊介绍:
ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels.
The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.