BNAlP-heterocycle。

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-02-05 DOI:10.1039/D5CC00308C

Tim Wellnitz, Leonie Wüst, Holger Braunschweig and Christian Hering-Junghans

引用次数: 0

摘要

我们报道了磷铝烯与其较轻的类似物亚氨基硼烷的[2+2]环化反应，得到了环上具有刘易斯碱性中心和酸性中心交替的四元balp杂环。描述了该杂环对烯烃和炔的反应性，得到链式分子和扩环物质。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A BNAlP-heterocycle†

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A BNAlP-heterocycle†

We report the [2+2]-cyclization reaction of a phosphaalumene with its lighter analog, an iminoborane, to give a species with a four-membered BNAlP-heterocycle with alternating Lewis basic and acidic centers in the ring. The reactivity of this heterocycle towards alkenes and alkynes is described, giving chain molecules and ring-expanded species.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.