Yongping Guo, Haoxuan Zeng, Taihui Chen and Xiaoli Wu
{"title":"LYH:Tb和LYH:Eu膜探针的一步合成及其在炭疽杆菌识别中的应用","authors":"Yongping Guo, Haoxuan Zeng, Taihui Chen and Xiaoli Wu","doi":"10.1039/D4DT03442B","DOIUrl":null,"url":null,"abstract":"<p >In this study, two new photoluminescent film probes (LYH:Tb and LYH:Eu) were developed through chemical bath deposition. Benefiting from the antenna effect of DPA, these films can enhance the characteristic fluorescence emission of Tb<small><sup>3+</sup></small> and Eu<small><sup>3+</sup></small> through energy transfer, enabling stable fluorescence detection of the anthrax spore biomarker, pyridine dicarboxylic acid (DPA). By adding various aromatic organic compounds for selectivity studies, it was found that their fluorescence responses were much lower than that of DPA, indicating that the LYH:Tb and LYH:Eu film probes exhibited excellent sensitivity and anti-interference properties for DPA detection. The detection limits of the LYH:Tb and LYH:Eu film probes are as low as 86 nM and 14 nM, respectively. Moreover, the film probe is characterized by its simple synthesis, convenient storage, excellent stability, rapid response, and suitability for visual monitoring.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 10","pages":" 4135-4141"},"PeriodicalIF":3.3000,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-step synthesis of LYH:Tb and LYH:Eu film probes and their application in Bacillus anthracis recognition†\",\"authors\":\"Yongping Guo, Haoxuan Zeng, Taihui Chen and Xiaoli Wu\",\"doi\":\"10.1039/D4DT03442B\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >In this study, two new photoluminescent film probes (LYH:Tb and LYH:Eu) were developed through chemical bath deposition. Benefiting from the antenna effect of DPA, these films can enhance the characteristic fluorescence emission of Tb<small><sup>3+</sup></small> and Eu<small><sup>3+</sup></small> through energy transfer, enabling stable fluorescence detection of the anthrax spore biomarker, pyridine dicarboxylic acid (DPA). By adding various aromatic organic compounds for selectivity studies, it was found that their fluorescence responses were much lower than that of DPA, indicating that the LYH:Tb and LYH:Eu film probes exhibited excellent sensitivity and anti-interference properties for DPA detection. The detection limits of the LYH:Tb and LYH:Eu film probes are as low as 86 nM and 14 nM, respectively. Moreover, the film probe is characterized by its simple synthesis, convenient storage, excellent stability, rapid response, and suitability for visual monitoring.</p>\",\"PeriodicalId\":71,\"journal\":{\"name\":\"Dalton Transactions\",\"volume\":\" 10\",\"pages\":\" 4135-4141\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2025-02-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dalton Transactions\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/dt/d4dt03442b\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/dt/d4dt03442b","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
One-step synthesis of LYH:Tb and LYH:Eu film probes and their application in Bacillus anthracis recognition†
In this study, two new photoluminescent film probes (LYH:Tb and LYH:Eu) were developed through chemical bath deposition. Benefiting from the antenna effect of DPA, these films can enhance the characteristic fluorescence emission of Tb3+ and Eu3+ through energy transfer, enabling stable fluorescence detection of the anthrax spore biomarker, pyridine dicarboxylic acid (DPA). By adding various aromatic organic compounds for selectivity studies, it was found that their fluorescence responses were much lower than that of DPA, indicating that the LYH:Tb and LYH:Eu film probes exhibited excellent sensitivity and anti-interference properties for DPA detection. The detection limits of the LYH:Tb and LYH:Eu film probes are as low as 86 nM and 14 nM, respectively. Moreover, the film probe is characterized by its simple synthesis, convenient storage, excellent stability, rapid response, and suitability for visual monitoring.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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