利用杂散辐射抑制和圆细胞增强激光吸收光谱原位诊断多热流体注入参数。

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL
Analytical Chemistry Pub Date : 2025-02-18 Epub Date: 2025-01-30 DOI:10.1021/acs.analchem.4c05883
Di Wang, Yan Lv, Yu Pu, Yushuang Li, Mingji Wang, Weidong Sun, Dong Li
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引用次数: 0

摘要

多热流体(MTF)成分比和注入参数是海上稠油开发的关键输入,如注入调整和监测、产能预测和发电机燃烧过程优化。在一个中试环境中,我们对两个标志性的注入参数——气水比(GWR)和不凝气体比(NCGP)——进行了同步现场诊断。提出了一种基于杂散辐射抑制和圆细胞增强策略集成的新型激光吸收光谱多气体传感器系统的系统级集成。设计了一种结构优化的光探测器前消光线,以减小高温辐射对吸收信号的影响。同时,突破了注射管内部尺寸对气体分子长程吸收的限制,吸光信号信噪比提高了3.42倍。本工作在实验室规模的MTF发电系统中进行了以柴油为主要燃料的实验测试。结果表明,水/CO2浓度的测量不确定度分别保持在±6.34%和±6.87%。不凝气中CO2的比例与现场数据相当,但不同注入温度下模拟系统的GWR远高于现场注入参数。该测量系统表现出卓越的稳定性和快速响应,标志着一个重要的里程碑,这是第一个在实验室台架测试中进行MTF注射参数原位诊断的报道实例。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

In-Situ Diagnostics of Multi-Thermal Fluid Injection Parameters Using Stray Radiation Suppression and Circular Cell-Enhanced Laser Absorption Spectroscopy.

In-Situ Diagnostics of Multi-Thermal Fluid Injection Parameters Using Stray Radiation Suppression and Circular Cell-Enhanced Laser Absorption Spectroscopy.

Multithermal fluid (MTF) component ratios and injection parameters are critical inputs in offshore heavy oil development, such as injection adjustment and monitoring, productivity prediction, and generator combustion process optimization. We implement simultaneous in situ diagnostics of two emblematic injection parameters, the gas-water ratio (GWR) and noncondensable gases proportion (NCGP), in a pilot-scale environment. A system-level integration of a novel laser absorption spectroscopy multigas sensor system based on integrating stray radiation suppression and a circular cell-enhanced strategy is proposed. A structurally optimized extinction thread in front of a photodetector is designed to reduce the absorption signal distortion under the influence of high-temperature radiation. Meanwhile, we break the limitation of the internal dimensions of the injection tube on the long-path absorption of gas molecules and improve the absorbance signal SNR by 3.42-fold. The present work performed experimental tests using diesel as the primary fuel in a laboratory-scale MTF generation system. The results show that the measurement uncertainties for H2O/CO2 concentrations are maintained at ±6.34% and ±6.87%, respectively. The proportion of CO2 in noncondensable gas is comparable to field data, but the GWR of the simulation system at different injection temperatures is much higher than that of the field injection parameters. The measurement system demonstrates remarkable stability and rapid response, marking a significant milestone as the first reported instance of in situ diagnostics of MTF injection parameters conducted in a laboratory bench test.

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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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