用于2,3-二氢苯并呋喃光合作用的黄酮桥联共轭多孔聚合物的串联构建

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-01-23 DOI:10.1039/d4cc06631f

Kuan Chen, Hailong Shen, Yansong Hu, Ji-Yu Liu, Kaixuan Guo, Zengxiang Wang, Qing Huang, Yuan Zhang

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引用次数: 0

摘要

采用串联法合成了含黄酮基团的共轭多孔聚合物。羰基化Sonogashira偶联与环化串联引导构建块的组装与伴随的黄酮骨架的生产。结果表明，在可见光照射下，FL-CPPs是苯酚与烯烃[3+2]环加成反应的高效无金属光催化剂。

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Tandem construction of flavone-bridged conjugated porous polymers for photosynthesis of 2,3-dihydrobenzofurans

Conjugated porous polymers bearing flavone moieties (FL-CPPs) were synthesized via a tandem approach. The carbonylative Sonogashira coupling in tandem with cyclization guided the assembling of building blocks with the accompanied production of flavone skeletons. The FL-CPPs were proved to be efficient metal-free photocatalysts for the [3+2] cycloaddition of phenols with olefins under the irradiation of visible-light.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.