电子给体-受体光活化形成C-S键的研究进展。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-01-14 DOI:10.1039/d4ob01951b

Sichang Wang , Liting Wang , Jin Cui , Liying Zhang , Qunzheng Zhang , Congyu Ke , Shenlin Huang

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引用次数: 0

摘要

最近通过电子给体-受体（EDA）复合物光活化形成C-S键的研究取得了显著进展。EDA配合物由电子给体和电子受体组成，在可见光照射下通过单电子转移事件在温和条件下促进C-S键的构建。本综述重点介绍了各种含硫底物，包括二乙酰氧基苯磺酰（DABSO）、磺酸、亚硫酸钠、磺酰氯化物和硫酚在eda促进的磺化和硫化反应中的应用，涵盖了自2017年以来发表的研究成果。这些反应为含硫化合物的合成提供了新颖、环保的途径。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Recent progress in C–S bond formation via electron donor–acceptor photoactivation

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Recent progress in C–S bond formation via electron donor–acceptor photoactivation

Recent advancements in C–S bond formation via electron donor–acceptor (EDA) complex photoactivation have been remarkable. EDA complexes, which are composed of electron donors and acceptors, facilitate C–S bond construction under mild conditions through single-electron transfer events upon visible light irradiation. This review highlights the utilization of various sulfur-containing substrates, including diacetoxybenzenesulfonyl (DABSO), sulfonic acids, sodium sulfinates, sulfonyl chlorides, and thiophenols, in EDA-promoted sulfonylation and thiolation reactions, covering the works published since 2017 to date. These reactions offer novel, environmentally friendly pathways for the synthesis of sulfur-containing compounds.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.