光滑金电极在桥接1,2,4-三草二烷-乙腈溶液中的电化学行为研究

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2025-01-17 DOI:10.1134/S0036024424702443

M. V. Polyakov, M. D. Vedenyapina, A. M. Skundin, I. A. Yaremenko, P. S. Radulov

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引用次数: 0

摘要

用循环伏安法和重量法研究了光滑金电极在乙腈中桥接1,2,4-三丙二烷介质中的行为。发现桥接1,2,4-三草烷分子中的过氧化物键在阴极过程中在电极表面被还原，随后形成二酮片段。在阳极氧化过程中检测胶体金颗粒的形成。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Studying the Electrochemical Behavior of a Smooth Gold Electrode in a Solution of Bridged 1,2,4-Trioxalane in Acetonitrile

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Studying the Electrochemical Behavior of a Smooth Gold Electrode in a Solution of Bridged 1,2,4-Trioxalane in Acetonitrile

Cyclic voltammetry and gravimetry are used to study the behavior of a smooth gold electrode in a medium of bridged 1,2,4-trioxalane in acetonitrile. It is found that the peroxide bond in the molecule of bridged 1,2,4-trioxalane is reduced on the surface of the electrode during the cathodic process, with the subsequent formation of a diketone fragment. The formation of colloidal gold particles is detected during anodic oxidation.

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.