烯烃饱和f2环

IF 16.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2025-01-14 DOI:10.1002/anie.202422899

Honggen Wang, Yin Li, Xiao-Bin Liu, Vadym Sham, Ivan Logvinenko, Jiang-Hao Xue, Jun-Yunzi Wu, Jia-Luo Fu, Shuang Lin, Yuan Liu, Qingjiang Li, Pavel K. Mykhailiuk

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引用次数: 0

摘要

现已开发出一种将简单的外环烯（无 Ar 取代基）转化为饱和 F2 环的通用方法。该反应涉及 IIII 试剂 C6F5I(OAc)2 (F5-PIDA)。该反应在毫克、克甚至多克级上都能有效进行。

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Saturated F2-rings from Alkenes

A general method to convert simple exocyclic alkenes (no Ar-substituents) into saturated F2-rings has been developed. The reaction involves the IIII-reagent C6F5I(OAc)2 (F5-PIDA). The reaction efficiently works on the mg-, g-, and even multigram scale.

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.