基于三（2,2,2-三氟乙基）亚磷酸盐的功能化二（2,2,2-三氟乙基）膦酸盐的合成

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-01-14 DOI:10.1007/s11172-024-4459-4

Yu. N. Bubnov, A. A. Prishchenko, M. V. Livantsov, O. P. Novikova, L. I. Livantsova, S. V. Baranin

引用次数: 0

摘要

以三（2,2,2-三氟乙基）亚磷酸酯为原料，以n -氯甲基胺羧酸和羰基化合物为原料，制备了方便的功能化二（2,2,2-三氟乙基）膦酸盐。所得到的化合物含有功能化的n -氨基甲基和磷酰基团，具有潜在的生物活性，是有效的萃取剂和多齿螯合配体，以及锂离子电池电解质的成分。

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Synthesis of functionalized bis(2,2,2-trifluoroethyl) phosphonates based on tris(2,2,2-trifluoroethyl) phosphite

Convenient synthesis of functionalized bis(2,2,2-trifluoroethyl) phosphonates based on tris(2,2,2-trifluoroethyl) phosphite using N-chloromethylamino carboxylic acids and carbonyl compounds has been developed. The resulting compounds containing functionalized N-amidomethyl and phosphoryl moieties have potential biological activity, and are of interest as effective extractants and polydentate chelating ligands, as well as components of lithium-ion battery electrolytes.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.