对映选择性银催化转化合成手性杂环化合物

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-02-24 DOI:10.1002/ejoc.202401284

Dr. Hélène Pellissier

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引用次数: 0

摘要

本文综述了2018年以来发表的通过银催化的对映选择性转化合成手性杂环的研究进展。手性银催化剂作为特殊温和的路易斯酸的能力被应用于发展1,3-偶极环加成、复杂的多米诺/串联反应和杂环化，从而实现高对映选择性的新型手性杂环产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of Chiral Heterocycles Through Enantioselective Silver‐Catalyzed Transformations

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Synthesis of Chiral Heterocycles Through Enantioselective Silver‐Catalyzed Transformations

This review collects the recent developments in the synthesis of chiral heterocycles through enantioselective silver‐catalyzed transformations published since 2018. It demonstrates the power of chiral silver catalysts as special mild Lewis acids to provide an impressive diversity of reaction pathways, such as 1,3‐dipolar cycloadditions, various types of cyclizations, along with a wide variety of more complex domino/tandem reactions, allowing many types of novel chiral heterocyclic products to be achieved in high enantioselectivities.

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.