涂有掺杂 PEDOT:PSS 的 DBD 等离子处理聚酯织物,用于热调节

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Cátia Magalhães, Ana Isabel Ribeiro, Rui Rodrigues, Ângela Meireles, Alexandra C. Alves, João Rocha, Fábio Pedroso de Lima, Marcos Martins, Bogdana Mitu, Veronica Satulu, Gheorghe Dinescu, Jorge Padrão, Andrea Zille
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引用次数: 0

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DBD plasma-treated polyester fabric coated with doped PEDOT:PSS for thermoregulation

DBD plasma-treated polyester fabric coated with doped PEDOT:PSS for thermoregulation
The manufacturing process of thermoregulation products with polyester (PES) fabric and conductive polymers such as poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT:PSS) with proper wearability, comfort, and high performance is still a challenge due to low adhesion, environment instability and non-uniform coatings. This study presents a simple and effective method for producing thermoregulatory PES fabrics using the Joule heating effect. Textiles treated with dielectric barrier discharge (DBD) plasma were functionalized with PEDOT:PSS incorporating secondary dopants, such as dimethyl sulfoxide (DMSO) and glycerol (GLY). PEDOT:PSS was used because it does not compromise the mechanical properties of base materials. DBD plasma treatment was applied to PES to improve the substrate’s functional groups and consequently increase adhesion and homogeneity of the PEDOT:PSS on the substrate. The polymer were applied to the textiles by dip-pad-dry-cure method ensuring uniform distribution and homogeneous heating of the materials. The samples’ conductivity, impedance, potential and Joule effect, and their morphological, chemical and thermal properties were studied. Control samples without plasma treatment and secondary dopants were also prepared. The results showed that the DBD-treated samples, coated with 5 layers of PEDOT:PSS, doped with DMSO 7 % (w/v), displayed the best conductivity and Joule effect performance reaching 44.3 °C after 1 h.
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来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
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