通过单电子转移触发的脱芳化重塑喹啉

IF 19.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chem Pub Date : 2024-12-12 DOI:10.1016/j.chempr.2024.11.007

Yun-Peng Chu , Jiajia Ma

引用次数: 0

摘要

在这一期的《化学》杂志上，Chiba Shunsuke教授、Derek Pratt教授和他们的同事报道了在多硫阴离子光催化下喹啉类化合物的脱芳二聚化和骨架重排的突破性研究。这项工作证明了一种独特的方法，通过单电子转移（SET）引发的一系列反应，将喹啉转化为复杂的富含sp3的多杂环和4-（3-吲哚甲基）喹啉。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Reshaping quinolines by single-electron-transfer-triggered dearomatization

In this issue of Chem, Prof. Shunsuke Chiba, Prof. Derek Pratt, and their colleagues report a groundbreaking study on the dearomative dimerization and skeletal rearrangement of quinolines under polysulfide anion photocatalysis. This work demonstrates a unique method for transforming quinolines into complex sp³-rich polyheterocycles and 4-(3-indolylmethyl)quinolines through a sequence of reactions initiated by single-electron transfer (SET).

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来源期刊

Chem Environmental Science-Environmental Chemistry

CiteScore

32.40

自引率

1.30%

发文量

281

期刊介绍： Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.