热定型温度对BOPET薄膜结构和性能的影响

IF 1 4区 化学 Q4 POLYMER SCIENCE
Shunliang Liao, Jin Guo, Yiguo Li, Zheng Shao, Xiukuan Liu, Zongbao Wang
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引用次数: 0

摘要

为了明确工艺参数对双轴取向聚对苯二甲酸乙二醇酯(BOPET)薄膜结构和性能的影响,采用双轴拉伸薄膜生产线制备了BOPET薄膜,通过DSC、WAXD、SAXS对其结构进行了表征,并对其力学、光学和热收缩性能进行了分析,探讨了热定型温度对BOPET薄膜结构和性能的影响。结果表明:随着热定型温度的升高,BOPET薄膜的机械方向拉伸强度(MD)降低,而横向断裂伸长率和弹性模量(TD)增加;BOPET薄膜的结晶度和长周期增加,雾度增加,透光率和光泽度变化不大。然而,MD和TD的热收缩率都有所下降。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of Heat-Setting Temperature on the Structure and Properties of BOPET Film

Effect of Heat-Setting Temperature on the Structure and Properties of BOPET Film

In order to clarify the influence of processing parameters on the structure and properties of biaxially oriented polyethylene terephthalate (BOPET) films, by preparing BOPET film using a biaxial stretching film production line, the structures were characterized by means of DSC, WAXD, SAXS and the mechanical, optical, and thermal shrinkage properties were analyzed to investigate the effects of heat-setting temperature on the structure and properties of BOPET films. The results showed that with the increase of heat-setting temperature, the tensile strength in the machine direction (MD) of BOPET film decreased, while the fracture elongation and elastic modulus in the transverse direction (TD) increased. In addition, the crystallinity and long period of BOPET films increased, haze increased, and the transmittance and glossiness showed little change. However, the thermal shrinkage rates in both MD and TD decreased.

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来源期刊
Polymer Science, Series A
Polymer Science, Series A 化学-高分子科学
CiteScore
1.70
自引率
0.00%
发文量
55
审稿时长
3 months
期刊介绍: Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.
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