用NiI2作为催化剂对氧环烷进行CO2加成：活化方法

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2024-12-06 DOI:10.1007/s11172-024-4426-0

S. E. Lyubimov, P. V. Cherkasova

{"title":"用NiI2作为催化剂对氧环烷进行CO2加成：活化方法","authors":"S. E. Lyubimov, P. V. Cherkasova","doi":"10.1007/s11172-024-4426-0","DOIUrl":null,"url":null,"abstract":"<div><p>Nickel(<span>ii</span>) iodide with organic and inorganic additives was tested in the addition of CO<sub>2</sub> to oxiranes. The introduction of diethylamine leads to the formation of an effective catalyst, which is, in some cases, capable of completing the reaction in the presence of 1 mol.% NiI<sub>2</sub> over a period of 1 h.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 10","pages":"3090 - 3093"},"PeriodicalIF":1.7000,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The use of NiI2 as a catalyst for CO2 addition to oxiranes: activation methods\",\"authors\":\"S. E. Lyubimov, P. V. Cherkasova\",\"doi\":\"10.1007/s11172-024-4426-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Nickel(<span>ii</span>) iodide with organic and inorganic additives was tested in the addition of CO<sub>2</sub> to oxiranes. The introduction of diethylamine leads to the formation of an effective catalyst, which is, in some cases, capable of completing the reaction in the presence of 1 mol.% NiI<sub>2</sub> over a period of 1 h.</p></div>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":\"73 10\",\"pages\":\"3090 - 3093\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-12-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11172-024-4426-0\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4426-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

用有机和无机添加剂对碘化镍（ii）进行了在氧环烷中添加CO2的试验。二乙胺的引入导致有效催化剂的形成，在某些情况下，它能够在1mol .% NiI2存在的情况下在1h内完成反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

The use of NiI2 as a catalyst for CO2 addition to oxiranes: activation methods

Nickel(ii) iodide with organic and inorganic additives was tested in the addition of CO₂ to oxiranes. The introduction of diethylamine leads to the formation of an effective catalyst, which is, in some cases, capable of completing the reaction in the presence of 1 mol.% NiI₂ over a period of 1 h.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.