Andrea Capucciati, Luca Baraglia, Elena Cassera, Daniele Merli, Luca Capaldo, Davide Ravelli
{"title":"在十钨酸盐介导的光电化学条件下将醇选择性氧化为羰基化合物","authors":"Andrea Capucciati, Luca Baraglia, Elena Cassera, Daniele Merli, Luca Capaldo, Davide Ravelli","doi":"10.1002/chem.202486504","DOIUrl":null,"url":null,"abstract":"<p><b>The Cover Feature</b> depicts the conversion of benzyl alcohols to the corresponding carbonyl compounds. The protocol, also extended to aliphatic derivatives, leverages the unique properties of the decatungstate anion in the role of photocatalyst. The transformation occurred smoothly under photoelectrochemical conditions, requiring the simultaneous irradiation and electrolysis of the reaction mixture, and delivered the desired products in high chemical yields and faradaic efficiencies. More information can be found in the Research Article by D. Ravelli and co-workers (DOI: 10.1002/chem.202402986). Artwork created by Elena Cassera.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 65","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486504","citationCount":"0","resultStr":"{\"title\":\"Selective Oxidation of Alcohols to Carbonyls under Decatungstate-Mediated Photoelectrochemical Conditions\",\"authors\":\"Andrea Capucciati, Luca Baraglia, Elena Cassera, Daniele Merli, Luca Capaldo, Davide Ravelli\",\"doi\":\"10.1002/chem.202486504\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>The Cover Feature</b> depicts the conversion of benzyl alcohols to the corresponding carbonyl compounds. The protocol, also extended to aliphatic derivatives, leverages the unique properties of the decatungstate anion in the role of photocatalyst. The transformation occurred smoothly under photoelectrochemical conditions, requiring the simultaneous irradiation and electrolysis of the reaction mixture, and delivered the desired products in high chemical yields and faradaic efficiencies. More information can be found in the Research Article by D. Ravelli and co-workers (DOI: 10.1002/chem.202402986). Artwork created by Elena Cassera.\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":144,\"journal\":{\"name\":\"Chemistry - A European Journal\",\"volume\":\"30 65\",\"pages\":\"\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2024-11-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486504\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - A European Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/chem.202486504\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - A European Journal","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/chem.202486504","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
封面特写描述了苄醇向相应羰基化合物的转化过程。该方案利用癸钨酸盐阴离子作为光催化剂的独特性质，也可扩展到脂肪族衍生物。转化过程在光电化学条件下顺利进行，需要同时对反应混合物进行照射和电解，并以较高的化学收率和法拉第效率得到所需的产物。更多信息，请参阅 D. Ravelli 及其合作者的研究文章（DOI: 10.1002/chem.202402986）。作品由 Elena Cassera 创作。
Selective Oxidation of Alcohols to Carbonyls under Decatungstate-Mediated Photoelectrochemical Conditions
The Cover Feature depicts the conversion of benzyl alcohols to the corresponding carbonyl compounds. The protocol, also extended to aliphatic derivatives, leverages the unique properties of the decatungstate anion in the role of photocatalyst. The transformation occurred smoothly under photoelectrochemical conditions, requiring the simultaneous irradiation and electrolysis of the reaction mixture, and delivered the desired products in high chemical yields and faradaic efficiencies. More information can be found in the Research Article by D. Ravelli and co-workers (DOI: 10.1002/chem.202402986). Artwork created by Elena Cassera.
期刊介绍：
Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields.
Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world.
All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times.
The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems.
Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
