前言通过芳基亚甲基环丙烷的氢硅烷化催化不对称构建 C 原子和 S 原子硅杂环戊烷

Liexin Wu, Dr. Lu Zhang, Dr. Jiandong Guo, Jihui Gao, Yang Ding, Dr. Jie Ke, Prof. Dr. Chuan He
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引用次数: 0

摘要

不对称氢硅烷化。在他们的通讯(e202413753)中,Chuan He 等人报告了一种高效的铜催化不对称级联氢硅烷化协议,该协议可快速组装碳和硅立体硅环戊烷,并具有良好至卓越的对映选择性和非对映选择性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Frontispiz: Catalytic Asymmetric Construction of C- and Si-Stereogenic Silacyclopentanes via Hydrosilylation of Arylmethylenecyclopropanes

Frontispiz: Catalytic Asymmetric Construction of C- and Si-Stereogenic Silacyclopentanes via Hydrosilylation of Arylmethylenecyclopropanes

Asymmetric Hydrosilylation. In their Communication (e202413753), Chuan He et al. report an efficient Cu-catalyzed asymmetric cascade hydrosilylation protocol, which allows the rapid assembly of carbon- and silicon-stereogenic silacyclopentanes with good to excellent enantioselectivities and diastereoselectivities.

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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