Nd3+ 离子激活的钠硼酸盐玻璃的合成、光致发光、judd-ofelt 参数和高能中子/带电粒子传输效率

IF 5.1 2区材料科学 Q1 MATERIALS SCIENCE, CERAMICS

Ceramics International Pub Date : 2024-09-26 DOI:10.1016/j.ceramint.2024.09.307

Alaa Hammoud , B. Alshahrani , Elena V. Stroganova , Valeriy A. Klimenko , Norah Alomayrah , Z.A. Alrowaili , I.O. Olarinoye , Chahkrit Sriwunkum , M.S. Al-Buriahi

{"title":"Nd3+ 离子激活的钠硼酸盐玻璃的合成、光致发光、judd-ofelt 参数和高能中子/带电粒子传输效率","authors":"Alaa Hammoud , B. Alshahrani , Elena V. Stroganova , Valeriy A. Klimenko , Norah Alomayrah , Z.A. Alrowaili , I.O. Olarinoye , Chahkrit Sriwunkum , M.S. Al-Buriahi","doi":"10.1016/j.ceramint.2024.09.307","DOIUrl":null,"url":null,"abstract":"<div><div>Sodium borate glasses doped with Nd3+ ions and having the molar formulations 75B2O3 – 15Na2O – 9.5x – 0.5Nd2O3, where x = Bi2O3; SrO and Li2O were prepared by employing the melt quenching technique. The glasses were coded as BiNd, SrNd, and LiNd for x = Bi2O3; SrO and Li2O, respectively. The prepared glasses were characterized for their physical and optical attributes. The influence of the glass composition on the photoluminescence and fast neutron (FN) and charged radiation (CR) transmission efficiencies were also investigated. The density of BiNd, SrNd, and LiNd is 3.32, 2.43, and 3.32 g/cm3, respectively. Optical constants of the glasses showed variations with glass composition. The FTIR study of the glass also revealed the structure of the glasses. The BiNd glass has the most intense PL of all the samples, followed by SrNd glass, while LiNd had the weakest PL emission. The value of <math><mrow><msub><mi>Σ</mi><mi>R</mi></msub></mrow></math> for BiNd, SiNd, and LiNd is 0.1029 cm−1, 0.1009 cm−1, and 0.0987 cm−1, respectively. The projected ranges of electrons, protons, helium ions, and carbon ions were generally lower for denser XNd glass. The XNd glasses are potentially useful of optical, shielding and dosimetry applications.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 23","pages":"Pages 49624-49633"},"PeriodicalIF":5.1000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, photoluminescence, judd-ofelt parameters, and high energy neutron/charged particle transmission efficiencies of Nd3+ ion-activated sodium-borate glasses\",\"authors\":\"Alaa Hammoud , B. Alshahrani , Elena V. Stroganova , Valeriy A. Klimenko , Norah Alomayrah , Z.A. Alrowaili , I.O. Olarinoye , Chahkrit Sriwunkum , M.S. Al-Buriahi\",\"doi\":\"10.1016/j.ceramint.2024.09.307\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Sodium borate glasses doped with Nd3+ ions and having the molar formulations 75B2O3 – 15Na2O – 9.5x – 0.5Nd2O3, where x = Bi2O3; SrO and Li2O were prepared by employing the melt quenching technique. The glasses were coded as BiNd, SrNd, and LiNd for x = Bi2O3; SrO and Li2O, respectively. The prepared glasses were characterized for their physical and optical attributes. The influence of the glass composition on the photoluminescence and fast neutron (FN) and charged radiation (CR) transmission efficiencies were also investigated. The density of BiNd, SrNd, and LiNd is 3.32, 2.43, and 3.32 g/cm3, respectively. Optical constants of the glasses showed variations with glass composition. The FTIR study of the glass also revealed the structure of the glasses. The BiNd glass has the most intense PL of all the samples, followed by SrNd glass, while LiNd had the weakest PL emission. The value of <math><mrow><msub><mi>Σ</mi><mi>R</mi></msub></mrow></math> for BiNd, SiNd, and LiNd is 0.1029 cm−1, 0.1009 cm−1, and 0.0987 cm−1, respectively. The projected ranges of electrons, protons, helium ions, and carbon ions were generally lower for denser XNd glass. The XNd glasses are potentially useful of optical, shielding and dosimetry applications.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 23\",\"pages\":\"Pages 49624-49633\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884224043414\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224043414","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}

引用次数: 0

摘要

采用熔融淬火技术制备了掺杂 Nd3+ 离子的硼酸钠玻璃，其摩尔形式为 75B2O3 - 15Na2O - 9.5x - 0.5Nd2O3，其中 x = Bi2O3；SrO 和 Li2O。当 x = Bi2O3、SrO 和 Li2O 时，这些玻璃分别命名为 BiNd、SrNd 和 LiNd。制备的玻璃具有物理和光学特性。此外，还研究了玻璃成分对光致发光、快中子（FN）和带电辐射（CR）传输效率的影响。BiNd、SrNd 和 LiNd 的密度分别为 3.32、2.43 和 3.32 g/cm3。玻璃的光学常数随玻璃成分的变化而变化。玻璃的傅立叶变换红外光谱研究也揭示了玻璃的结构。在所有样品中，BiNd 玻璃的聚光强度最高，其次是 SrNd 玻璃，而 LiNd 的聚光强度最弱。BiNd、SiNd 和 LiNd 的 ΣR 值分别为 0.1029 cm-1、0.1009 cm-1 和 0.0987 cm-1。密度较高的 XNd 玻璃的电子、质子、氦离子和碳离子的投影范围普遍较低。XNd 玻璃可用于光学、屏蔽和剂量测定。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis, photoluminescence, judd-ofelt parameters, and high energy neutron/charged particle transmission efficiencies of Nd3+ ion-activated sodium-borate glasses

Sodium borate glasses doped with Nd³⁺ ions and having the molar formulations 75B₂O₃ – 15Na₂O – 9.5x – 0.5Nd₂O₃, where x = Bi₂O₃; SrO and Li₂O were prepared by employing the melt quenching technique. The glasses were coded as BiNd, SrNd, and LiNd for x = Bi₂O₃; SrO and Li₂O, respectively. The prepared glasses were characterized for their physical and optical attributes. The influence of the glass composition on the photoluminescence and fast neutron (FN) and charged radiation (CR) transmission efficiencies were also investigated. The density of BiNd, SrNd, and LiNd is 3.32, 2.43, and 3.32 g/cm³, respectively. Optical constants of the glasses showed variations with glass composition. The FTIR study of the glass also revealed the structure of the glasses. The BiNd glass has the most intense PL of all the samples, followed by SrNd glass, while LiNd had the weakest PL emission. The value of

Σ_{R}

for BiNd, SiNd, and LiNd is 0.1029 cm⁻¹, 0.1009 cm⁻¹, and 0.0987 cm⁻¹, respectively. The projected ranges of electrons, protons, helium ions, and carbon ions were generally lower for denser XNd glass. The XNd glasses are potentially useful of optical, shielding and dosimetry applications.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Ceramics International 工程技术-材料科学：硅酸盐

CiteScore

9.40

自引率

15.40%

发文量

4558

审稿时长

25 days

期刊介绍： Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties. Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour. Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.