{"title":"2-[4-(Dibutylamino)-2-hydroxybenzoyl] Benzoic Acid 在 12 种纯溶剂中的平衡溶解度测定、相关性和汉森溶解度参数","authors":"Haoran Li, Shouxiang Jiang, Xiangyu Sun, Wenjun Xie, Chengfei Wang, Xin Huang, Xia Jiang, Yongjin Zou, Gengxiu Zheng* and Guan Wang*, ","doi":"10.1021/acs.jced.4c0044510.1021/acs.jced.4c00445","DOIUrl":null,"url":null,"abstract":"<p >The solubility of 2-[4-(dibutylamino)-2-hydroxy-benzoyl] benzoic acid (BBA) was determined in 12 pure solvents using the static equilibrium method. The measurements were taken at temperatures ranging from 283.15 to 323.15 K. The results indicated a positive relationship between the solubility of BBA and the temperature in the 12 pure solvents, and BBA exhibited the highest solubility in <i>n</i>-propanol and the lowest solubility in <i>n</i>-heptane. In addition, the modified Apelblat, Van’t Hoff, λ<i>h</i>, and Wilson models were used to establish a correlation with the experimental solubility of BBA. The correlation analysis revealed a strong concordance between the experimental and estimated values. Furthermore, the solubility characteristics of BBA were further examined by utilizing Hansen’s solubility parameter. The results revealed that the dissolution of BBA in solvents is a multifaceted process, influenced by various parameters rather than solution polarity and HSP. The thermodynamic properties of the mixture of BBA in 12 pure solvents were also evaluated based on the measured solubility data and the parameter values of the Wilson model.</p>","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"69 11","pages":"4186–4196 4186–4196"},"PeriodicalIF":2.0000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Equilibrium Solubility Determination, Correlation, and Hansen Solubility Parameters of 2-[4-(Dibutylamino)-2-hydroxybenzoyl] Benzoic Acid in 12 Pure Solvents\",\"authors\":\"Haoran Li, Shouxiang Jiang, Xiangyu Sun, Wenjun Xie, Chengfei Wang, Xin Huang, Xia Jiang, Yongjin Zou, Gengxiu Zheng* and Guan Wang*, \",\"doi\":\"10.1021/acs.jced.4c0044510.1021/acs.jced.4c00445\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The solubility of 2-[4-(dibutylamino)-2-hydroxy-benzoyl] benzoic acid (BBA) was determined in 12 pure solvents using the static equilibrium method. The measurements were taken at temperatures ranging from 283.15 to 323.15 K. The results indicated a positive relationship between the solubility of BBA and the temperature in the 12 pure solvents, and BBA exhibited the highest solubility in <i>n</i>-propanol and the lowest solubility in <i>n</i>-heptane. In addition, the modified Apelblat, Van’t Hoff, λ<i>h</i>, and Wilson models were used to establish a correlation with the experimental solubility of BBA. The correlation analysis revealed a strong concordance between the experimental and estimated values. Furthermore, the solubility characteristics of BBA were further examined by utilizing Hansen’s solubility parameter. The results revealed that the dissolution of BBA in solvents is a multifaceted process, influenced by various parameters rather than solution polarity and HSP. The thermodynamic properties of the mixture of BBA in 12 pure solvents were also evaluated based on the measured solubility data and the parameter values of the Wilson model.</p>\",\"PeriodicalId\":42,\"journal\":{\"name\":\"Journal of Chemical & Engineering Data\",\"volume\":\"69 11\",\"pages\":\"4186–4196 4186–4196\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2024-10-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical & Engineering Data\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.jced.4c00445\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical & Engineering Data","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.jced.4c00445","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Equilibrium Solubility Determination, Correlation, and Hansen Solubility Parameters of 2-[4-(Dibutylamino)-2-hydroxybenzoyl] Benzoic Acid in 12 Pure Solvents
The solubility of 2-[4-(dibutylamino)-2-hydroxy-benzoyl] benzoic acid (BBA) was determined in 12 pure solvents using the static equilibrium method. The measurements were taken at temperatures ranging from 283.15 to 323.15 K. The results indicated a positive relationship between the solubility of BBA and the temperature in the 12 pure solvents, and BBA exhibited the highest solubility in n-propanol and the lowest solubility in n-heptane. In addition, the modified Apelblat, Van’t Hoff, λh, and Wilson models were used to establish a correlation with the experimental solubility of BBA. The correlation analysis revealed a strong concordance between the experimental and estimated values. Furthermore, the solubility characteristics of BBA were further examined by utilizing Hansen’s solubility parameter. The results revealed that the dissolution of BBA in solvents is a multifaceted process, influenced by various parameters rather than solution polarity and HSP. The thermodynamic properties of the mixture of BBA in 12 pure solvents were also evaluated based on the measured solubility data and the parameter values of the Wilson model.
期刊介绍：
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.
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