Kwanghwi Kim, Hyunji Lim, Jieun Kim, Gicheol Jeong, Jo Hong Kang, Hyun Sic Park, Jinwon Park, Sweety Verma* and Hojun Song*,
{"title":"作为二氧化碳捕获混合吸收剂的哌嗪+甘氨酸水溶液的物理性质","authors":"Kwanghwi Kim, Hyunji Lim, Jieun Kim, Gicheol Jeong, Jo Hong Kang, Hyun Sic Park, Jinwon Park, Sweety Verma* and Hojun Song*, ","doi":"10.1021/acs.jced.4c0013910.1021/acs.jced.4c00139","DOIUrl":null,"url":null,"abstract":"<p >The density, vapor pressure, and dynamic viscosity of piperazine (PZ) + glycine solutions were measured for various equimolal concentration ranges (<i>m</i><sub>PZ and Gly</sub> = (0.501–3.009)) at 0.1 MPa pressure and temperature ranging from 303.15 to 353.15 K. The diffusion coefficient, thermal expansion coefficient, and viscosity activation energy values were computed based on the measured data of density and dynamic viscosity. These physical properties data would be of great significance for designing post-combustion CO<sub>2</sub> capture systems utilizing PZ-based absorbent blended with aqueous amino acids solutions. The investigation of data on physical properties revealed that as the molality of the PZ-glycine solution increases, both the density and viscosity increase, whereas the vapor pressure decreases. Moreover, as the temperature rises, the density and dynamic viscosity decrease, while the vapor pressure increases.</p>","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":"69 11","pages":"3689–3697 3689–3697"},"PeriodicalIF":2.0000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Physical Properties of Aqueous Piperazine + Glycine Solutions as Blended Absorbent for Carbon Dioxide Capture\",\"authors\":\"Kwanghwi Kim, Hyunji Lim, Jieun Kim, Gicheol Jeong, Jo Hong Kang, Hyun Sic Park, Jinwon Park, Sweety Verma* and Hojun Song*, \",\"doi\":\"10.1021/acs.jced.4c0013910.1021/acs.jced.4c00139\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The density, vapor pressure, and dynamic viscosity of piperazine (PZ) + glycine solutions were measured for various equimolal concentration ranges (<i>m</i><sub>PZ and Gly</sub> = (0.501–3.009)) at 0.1 MPa pressure and temperature ranging from 303.15 to 353.15 K. The diffusion coefficient, thermal expansion coefficient, and viscosity activation energy values were computed based on the measured data of density and dynamic viscosity. These physical properties data would be of great significance for designing post-combustion CO<sub>2</sub> capture systems utilizing PZ-based absorbent blended with aqueous amino acids solutions. The investigation of data on physical properties revealed that as the molality of the PZ-glycine solution increases, both the density and viscosity increase, whereas the vapor pressure decreases. Moreover, as the temperature rises, the density and dynamic viscosity decrease, while the vapor pressure increases.</p>\",\"PeriodicalId\":42,\"journal\":{\"name\":\"Journal of Chemical & Engineering Data\",\"volume\":\"69 11\",\"pages\":\"3689–3697 3689–3697\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2024-10-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical & Engineering Data\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.jced.4c00139\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical & Engineering Data","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.jced.4c00139","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Physical Properties of Aqueous Piperazine + Glycine Solutions as Blended Absorbent for Carbon Dioxide Capture
The density, vapor pressure, and dynamic viscosity of piperazine (PZ) + glycine solutions were measured for various equimolal concentration ranges (mPZ and Gly = (0.501–3.009)) at 0.1 MPa pressure and temperature ranging from 303.15 to 353.15 K. The diffusion coefficient, thermal expansion coefficient, and viscosity activation energy values were computed based on the measured data of density and dynamic viscosity. These physical properties data would be of great significance for designing post-combustion CO2 capture systems utilizing PZ-based absorbent blended with aqueous amino acids solutions. The investigation of data on physical properties revealed that as the molality of the PZ-glycine solution increases, both the density and viscosity increase, whereas the vapor pressure decreases. Moreover, as the temperature rises, the density and dynamic viscosity decrease, while the vapor pressure increases.
期刊介绍:
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.