作为二氧化碳捕获混合吸收剂的哌嗪+甘氨酸水溶液的物理性质

IF 2 3区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY
Kwanghwi Kim, Hyunji Lim, Jieun Kim, Gicheol Jeong, Jo Hong Kang, Hyun Sic Park, Jinwon Park, Sweety Verma* and Hojun Song*, 
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引用次数: 0

摘要

在 0.1 MPa 压力和 303.15 至 353.15 K 温度范围内,测量了哌嗪 (PZ) + 甘氨酸溶液在不同等摩尔浓度范围(mPZ 和 Gly = (0.501-3.009))下的密度、蒸汽压和动态粘度。这些物理性质数据对于利用 PZ 基吸收剂与氨基酸水溶液混合设计燃烧后二氧化碳捕获系统具有重要意义。物理性质数据调查显示,随着 PZ-甘氨酸溶液摩尔数的增加,密度和粘度都会增加,而蒸汽压则会降低。此外,随着温度升高,密度和动态粘度降低,而蒸气压升高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Physical Properties of Aqueous Piperazine + Glycine Solutions as Blended Absorbent for Carbon Dioxide Capture

Physical Properties of Aqueous Piperazine + Glycine Solutions as Blended Absorbent for Carbon Dioxide Capture

The density, vapor pressure, and dynamic viscosity of piperazine (PZ) + glycine solutions were measured for various equimolal concentration ranges (mPZ and Gly = (0.501–3.009)) at 0.1 MPa pressure and temperature ranging from 303.15 to 353.15 K. The diffusion coefficient, thermal expansion coefficient, and viscosity activation energy values were computed based on the measured data of density and dynamic viscosity. These physical properties data would be of great significance for designing post-combustion CO2 capture systems utilizing PZ-based absorbent blended with aqueous amino acids solutions. The investigation of data on physical properties revealed that as the molality of the PZ-glycine solution increases, both the density and viscosity increase, whereas the vapor pressure decreases. Moreover, as the temperature rises, the density and dynamic viscosity decrease, while the vapor pressure increases.

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来源期刊
Journal of Chemical & Engineering Data
Journal of Chemical & Engineering Data 工程技术-工程:化工
CiteScore
5.20
自引率
19.20%
发文量
324
审稿时长
2.2 months
期刊介绍: The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.
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