用于聚二甲基硅氧烷化学的叠氮烷烃环化反应

IF 4.1 2区化学 Q2 POLYMER SCIENCE

Polymer Chemistry Pub Date : 2024-11-15 DOI:10.1039/D4PY01052C

Kseniya A. Bezlepkina, Sergey A. Milenin and Aziz M. Muzafarov

{"title":"用于聚二甲基硅氧烷化学的叠氮烷烃环化反应","authors":"Kseniya A. Bezlepkina, Sergey A. Milenin and Aziz M. Muzafarov","doi":"10.1039/D4PY01052C","DOIUrl":null,"url":null,"abstract":"<p >Polydimethylsiloxanes (PDMSs) occupy a special place among polymers due to their unique properties, including the possibility of their easy functionalization. Click chemistry reactions, in particular, the azide–alkyne cycloaddition reaction, are promising for the production of both functional siloxanes and siloxane copolymers, and for cross-linked materials. This review discusses the emergence and development of the azide–alkyne cycloaddition reaction for the synthesis and modification of polydimethylsiloxanes and structures based on them, as well as methods for introducing azide and acetylene fragments into the PDMS structure.</p>","PeriodicalId":100,"journal":{"name":"Polymer Chemistry","volume":" 48","pages":" 4917-4946"},"PeriodicalIF":4.1000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Azide–alkyne cycloaddition for polydimethylsiloxane chemistry\",\"authors\":\"Kseniya A. Bezlepkina, Sergey A. Milenin and Aziz M. Muzafarov\",\"doi\":\"10.1039/D4PY01052C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Polydimethylsiloxanes (PDMSs) occupy a special place among polymers due to their unique properties, including the possibility of their easy functionalization. Click chemistry reactions, in particular, the azide–alkyne cycloaddition reaction, are promising for the production of both functional siloxanes and siloxane copolymers, and for cross-linked materials. This review discusses the emergence and development of the azide–alkyne cycloaddition reaction for the synthesis and modification of polydimethylsiloxanes and structures based on them, as well as methods for introducing azide and acetylene fragments into the PDMS structure.</p>\",\"PeriodicalId\":100,\"journal\":{\"name\":\"Polymer Chemistry\",\"volume\":\" 48\",\"pages\":\" 4917-4946\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/py/d4py01052c\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/py/d4py01052c","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}

引用次数: 0

摘要

多二甲基硅氧烷（PDMS）因其独特的性能，包括易于功能化的可能性，在聚合物中占有特殊的地位。点击化学反应，尤其是叠氮烷烃环加成反应，对于生产功能硅氧烷和硅氧烷共聚物以及交联材料都很有前景。本综述讨论了叠氮-炔烃环加成反应在合成聚二甲基硅氧烷改性物及其结构方面的出现和发展，以及将叠氮和炔烃片段引入 PDMS 结构的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Azide–alkyne cycloaddition for polydimethylsiloxane chemistry

查看原文本刊更多论文

Azide–alkyne cycloaddition for polydimethylsiloxane chemistry

Polydimethylsiloxanes (PDMSs) occupy a special place among polymers due to their unique properties, including the possibility of their easy functionalization. Click chemistry reactions, in particular, the azide–alkyne cycloaddition reaction, are promising for the production of both functional siloxanes and siloxane copolymers, and for cross-linked materials. This review discusses the emergence and development of the azide–alkyne cycloaddition reaction for the synthesis and modification of polydimethylsiloxanes and structures based on them, as well as methods for introducing azide and acetylene fragments into the PDMS structure.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Polymer Chemistry POLYMER SCIENCE-

CiteScore

8.60

自引率

8.70%

发文量

535

审稿时长

1.7 months

期刊介绍： Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.