{"title":"磺酸封端长侧链聚羧酸盐超塑化剂的合成、性能评估和吸附分散机理。","authors":"Haotian Duan, Tianfeng Zhou, Beibei Li, Yuxia Pang, Hongming Lou, Dongjie Yang, Xueqing Qiu","doi":"10.1021/acs.langmuir.4c03026","DOIUrl":null,"url":null,"abstract":"<p><p>Polycarboxylate superplasticizers (PCEs) achieve dispersion mainly via steric hindrance from poly(ether) side chains. However, long side chains may cause structural collapse. This study mitigates this issue by introducing sulfonic acid terminations to the long side chains, synthesizing sulfonic-terminated polycarboxylates (PCEPS). Electrostatic repulsion between sulfonic and carboxyl groups on the main chain reduces the level of collapse, enhancing PCE dispersion in cement. PCEPS-4000 showed the strongest dispersion compared with conventional PCEs (PCEC). PCEPS-4000 formed an adsorption layer thickness (ALT) of 11.65 nm, showing a significant improvement over the 7.93 nm observed in the carboxyl-terminated long side chain polycarboxylate (PCETA). Stronger negative charge and lower complexation of sulfonic acid groups enhance the side chain extension. PCEPS also shows good clay tolerance and slump retention, proving its versatility as a concrete admixture.</p>","PeriodicalId":50,"journal":{"name":"Langmuir","volume":" ","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Performance Evaluation, and Adsorption-Dispersion Mechanism of Sulfonic Acid-Terminated Long Side Chain Polycarboxylate Superplasticizers.\",\"authors\":\"Haotian Duan, Tianfeng Zhou, Beibei Li, Yuxia Pang, Hongming Lou, Dongjie Yang, Xueqing Qiu\",\"doi\":\"10.1021/acs.langmuir.4c03026\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Polycarboxylate superplasticizers (PCEs) achieve dispersion mainly via steric hindrance from poly(ether) side chains. However, long side chains may cause structural collapse. This study mitigates this issue by introducing sulfonic acid terminations to the long side chains, synthesizing sulfonic-terminated polycarboxylates (PCEPS). Electrostatic repulsion between sulfonic and carboxyl groups on the main chain reduces the level of collapse, enhancing PCE dispersion in cement. PCEPS-4000 showed the strongest dispersion compared with conventional PCEs (PCEC). PCEPS-4000 formed an adsorption layer thickness (ALT) of 11.65 nm, showing a significant improvement over the 7.93 nm observed in the carboxyl-terminated long side chain polycarboxylate (PCETA). Stronger negative charge and lower complexation of sulfonic acid groups enhance the side chain extension. PCEPS also shows good clay tolerance and slump retention, proving its versatility as a concrete admixture.</p>\",\"PeriodicalId\":50,\"journal\":{\"name\":\"Langmuir\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Langmuir\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.langmuir.4c03026\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.langmuir.4c03026","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis, Performance Evaluation, and Adsorption-Dispersion Mechanism of Sulfonic Acid-Terminated Long Side Chain Polycarboxylate Superplasticizers.
Polycarboxylate superplasticizers (PCEs) achieve dispersion mainly via steric hindrance from poly(ether) side chains. However, long side chains may cause structural collapse. This study mitigates this issue by introducing sulfonic acid terminations to the long side chains, synthesizing sulfonic-terminated polycarboxylates (PCEPS). Electrostatic repulsion between sulfonic and carboxyl groups on the main chain reduces the level of collapse, enhancing PCE dispersion in cement. PCEPS-4000 showed the strongest dispersion compared with conventional PCEs (PCEC). PCEPS-4000 formed an adsorption layer thickness (ALT) of 11.65 nm, showing a significant improvement over the 7.93 nm observed in the carboxyl-terminated long side chain polycarboxylate (PCETA). Stronger negative charge and lower complexation of sulfonic acid groups enhance the side chain extension. PCEPS also shows good clay tolerance and slump retention, proving its versatility as a concrete admixture.
期刊介绍：
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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