苯胺与乙烯基氮丙啶在六氟异丙醇中的正烯丙基化反应

IF 5.4 3区材料科学 Q2 CHEMISTRY, PHYSICAL

ACS Applied Energy Materials Pub Date : 2024-11-14 DOI:10.1039/d4qo01719f

Jing-Jing Nie, Zhong-Xia Wang

引用次数: 0

摘要

在六氟异丙醇中，N,N-二烷基苯胺与 1-磺酰基-2-乙烯基氮丙啶在空气中进行无过渡金属反应，可获得中等至极好收率的正烯丙基苯胺。该反应还具有反应条件温和、正单烯丙基化选择性高、C-C 双键为 E 构型、底物范围广以及官能团兼容性好等特点。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Ortho-allylation of anilines with vinylaziridines in hexafluoroisopropanol

Transition-metal-free reaction of N,N-dialkylanilines with 1-sulfonyl-2-vinylaziridines in hexafluoroisopropanol in air gave ortho-allylated anilines in moderate to excellent yields. The reaction also features mild reaction conditions, ortho-monoallylation selectivity, E-configurated C-C double bonds, wide substrate scope and good compatibility of functional groups.

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来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.