Shu-Ran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guang-Juan Xu, Wei Xie, Na Xu, Yan-Hong Xu and Ya-Qian Lan
{"title":"具有不同聚集形态的 UiO-66-NH2 的二氧化碳光还原活性各异","authors":"Shu-Ran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guang-Juan Xu, Wei Xie, Na Xu, Yan-Hong Xu and Ya-Qian Lan","doi":"10.1039/D4CC04919E","DOIUrl":null,"url":null,"abstract":"<p >Several kinds of UiO-66-NH<small><sub>2</sub></small> with different aggregation morphologies were prepared to verify that the morphology of the photocatalyst could influence charge transfer. That showing poor aggregation exhibits superior CO<small><sub>2</sub></small> photoreduction performance, attributed to the small particle size related to the poor aggregation and to the resulting high efficiency of separation of photogenerated electrons and holes.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" 98","pages":" 14641-14644"},"PeriodicalIF":4.3000,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Varied CO2 photoreduction activities of UiO-66-NH2 MOFs with different aggregation morphologies†\",\"authors\":\"Shu-Ran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guang-Juan Xu, Wei Xie, Na Xu, Yan-Hong Xu and Ya-Qian Lan\",\"doi\":\"10.1039/D4CC04919E\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Several kinds of UiO-66-NH<small><sub>2</sub></small> with different aggregation morphologies were prepared to verify that the morphology of the photocatalyst could influence charge transfer. That showing poor aggregation exhibits superior CO<small><sub>2</sub></small> photoreduction performance, attributed to the small particle size related to the poor aggregation and to the resulting high efficiency of separation of photogenerated electrons and holes.</p>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\" 98\",\"pages\":\" 14641-14644\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-11-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc04919e\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc04919e","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
为了验证光催化剂的形态对电荷转移的影响,我们制备了不同聚集形态的 UiO-66-NH2。其中,聚集度较差的 UiO-66-NH2 在 CO2 光还原中表现出更优越的性能,这是因为聚集度较差的 UiO-66-NH2 粒径小,光生电子孔的分离效率高。
Varied CO2 photoreduction activities of UiO-66-NH2 MOFs with different aggregation morphologies†
Several kinds of UiO-66-NH2 with different aggregation morphologies were prepared to verify that the morphology of the photocatalyst could influence charge transfer. That showing poor aggregation exhibits superior CO2 photoreduction performance, attributed to the small particle size related to the poor aggregation and to the resulting high efficiency of separation of photogenerated electrons and holes.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.